Module 4 - Basics of Organic Chemistry Flashcards

1
Q

What does nomenclature
mean?

A

The system used for naming organic
compounds

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2
Q

What does the term empirical
formula mean?

A

Simplest whole number ratio of atoms in
a molecule

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3
Q

What does the term molecular
formula mean?

A

It provides the actual number of atoms of
different elements in a molecule

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4
Q

What does the term displayed
formula mean?

A

It shows every atom and every bond in a
molecule

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5
Q

What does the term structural
formula mean?

A

It shows the arrangement of atoms in a
molecule without showing every bond

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6
Q

Define skeletal formula

A

A type of formula which is drawn as lines
with each vertex being a carbon atom.
Carbon atoms not drawn, assumed each
C atom has all unspecified bonds as C-H

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7
Q

Define homologous series

A

A series of organic compounds having
the same functional group but with each
successive member differing by CH2

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8
Q

What is a functional group?

A

A group of atoms responsible for
characteristic reactions of a compound

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9
Q

What is an aliphatic
hydrocarbon?

A

Hydrocarbon with carbon atoms joined
together in a straight line or branched
chain

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10
Q

What is an alicyclic
hydrocarbon?

A

Hydrocarbons arranged in non aromatic
rings with or without side chains

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11
Q

What is an aromatic
hydrocarbon?

A

Hydrocarbon that contains at least one
benzene ring

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12
Q

Give the suffixes for:
a) No double bonds
b) At least one double bond
c) An alcohol
d) An aldehyde
e) A ketone
f) A carboxylic acid

A

a) No double bonds -ane
b) At least one double bond -ene
c) An alcohol -ol
d) An aldehyde -al
e) A ketone -one
f) A carboxylic acid -oic acid

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13
Q

Give the prefixes for:
a) CH3 group
b) C2H5 group
c) C3H7 group
d) C4H9 group
e) Cl group
f) Br group
g) I group

A

a) CH3 group methyl
b) C2H5 group ethyl
c) C3H7 group propyl
d) C4H9 group butyl
e) Cl group chlorof) Br group bromo
g) I group iodo

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14
Q

What is the general formula of
alkanes?

A

CnH2n+2

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15
Q

What is the general formula of
alkenes?

A

CnH2n

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16
Q

What is the general formula of
alcohols?

A

CnH2n+1OH

17
Q

What does saturated mean?

A

Organic compounds which only contain
single bonds

18
Q

What are unsaturated
compounds?

A

Organic compounds that contain at least
one carbon carbon double covalent bond

19
Q

Define structural isomerism

A

When molecules have the same molecular
formula but different structural formula

20
Q

What are the 3 ways in which
structural isomers can be
formed?

A
  1. Alkyl groups can be in different places
  2. Functional groups can be bonded to
    different parts
  3. There can be different functional groups
21
Q

What are stereoisomers?

A

Organic compounds with the same
molecular formula but have different
arrangement of atoms in space

22
Q

What is E-Z isomerism and
how are the E and Z isomers
decided?

A

E-Z isomerism is caused by the limited rotation about C=C
double bonds
If the two substituents with the highest molecular mass are on
the same side of the double bond, it is the Z (zusammen)
isomer
If they are on different sides, it is the E (entgegen) isomer

23
Q

What is Cis-trans isomerism?

A

Special type of E/Z isomerism where the
two substituents on each carbon atom
are the same

24
Q

What is homolytic fission?

A

It happens when each bonding atom
receives one electron from the bonded
pair forming two radicals

25
Q

What is heterolytic fission?

A

When one bonding atom receives both
electrons from the bonded pair

26
Q

What are radicals?

A

Highly reactive, neutral species

27
Q

How is a covalent bond
formed from two radicals?

A

The radicals collide and the electrons are
involved the bond formation