Module 3 - Periodicity Flashcards
How are the elements
arranged in a periodic table?
They are arranged in the order of
increasing atomic numbers
What is a period on a periodic
table?
The horizontal rows in the periodic table
What is a group on a periodic
table?
The vertical columns
What is meant by periodicity?
The repeating trends in chemical and
physical properties
What change happens across
each period?
Elements change from metals to non
metals
How can the electron
configuration be written in
short?
The noble gas before the element is
used to abbreviate
E.g Li → 1s2 2s1 ; Li → [He] 2s1
Define first ionisation energy
The energy required to remove one
electron from each atom in one mole of
the gaseous element to form one mole of
gaseous 1+ ions
Write an equation for the first
ionisation energy of
magnesium
Mg (g) → Mg+ (g) + e-
What are the factors that affect
ionisation energy?
● Atomic radius
● Nuclear charge
● Electron shielding or screening
Explain the trend of period 3
First Ionisation energy increases across period 3 because of:
-Increased nuclear charge
-Decreased atomic radius
-Same electron shielding
which means more energy is needed to remove the first electron.
Dips at Al because: outer electron is in a 3p orbital, higher energy than 3s orbital → less
energy needed to remove electron
Dips at S because one 3p orbital contains two electrons → repulsion between paired
electrons → less energy needed to remove one
Why does first ionisation
energy decrease between
group 2 to 3?
● Decrease between 2 to 3 because in group 3
the outermost electrons are in p orbitals
whereas in group 2 they are in s orbital, so the
electrons are easier to be removed
Why does first ionisation
energy decrease between
group 5 to 6?
The decrease between 5 to 6 is due to the group
5 electrons in p orbital are single electrons and in
group 6 the outermost electrons are spin paired,
with some repulsion. Therefore the electrons are
slightly easier to remove
Does first ionisation increase
or decrease between the end
of one period and the start of
next? Why?
Decrease
● There is increase in atomic radius
● Increase in electron shielding
Does first ionisation increase
or decrease down a group?
Why?
● Decrease
● Shielding increases → weaker attraction
● Atomic radius increases → distance between the outer
electrons and nucleus increases → weaker attraction
● Increase in number of protons is outweighed by increase
in distance and shielding
What are the properties of
giant metallic lattices?
4 points
● High melting and boiling point
● Good electrical conductors
● Malleability
● Ductility