Module 1 Flashcards

1
Q

Refers to the electrostatic force holding two ions together due to their differing charges

A

Ionic bond

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2
Q

___ result from the transfer of one or more electrons from one atom to another

A

Ions

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3
Q

Ions that lose an electron

A

Cation

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4
Q

A non-metal atom that gains an electron

A

Anion

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5
Q

Ionic bonding is actually a CONSEQUENCE
of ___

A

Ionization

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6
Q

___ have a tendency to lose electrons

A

Metals

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7
Q

___ have a tendency to gain electrons

A

Non-metals

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8
Q

“To have eight valence electrons”

A

Octet rule

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9
Q

Hydrogens love having a ___ bond

A

Single

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10
Q

Covalent bond classifications

Overlap of electron clouds which allow bond rotation

A

Sigma bonds (single bonds)

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11
Q

Covalent bond classifications

Bonds which arise from electron clouds which do not allow bond rotation

A

Pi bonds

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12
Q

Covalent bonds are also known as?

A

Molecular orbitals

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13
Q

Properties of a Covalent Bond

Refers to the number of electron pairs shared by a pair of atoms involved in a covalent bond

A

Bond order

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14
Q

Properties of a Covalent Bond

Refers to the energy required to overcome the forces of attraction between the atoms, Silberberg (2013)

A

Bond energy

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15
Q

Bond energy

It is easier to break the attraction involving ___ bonds as compared to triple bonds

A

Single

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16
Q

Properties of a Covalent Bond

  • Distance between the nuclei of two atoms involved in a covalent bond
  • Usually measured in picometers (pm)
A

Bond length

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17
Q

“For a given pair of atoms, a higher bond order results in a ___ bond length and a ___ bond energy.” (Silberberg, 2013)

A

Shorter; Higher

18
Q

Lower or Higher

Covalent compounds, whichever state they are, usually have ___ boiling and melting points compared to ionic compounds

A

Lower

19
Q

Covalent or Ionic compounds?

  • Do not have freely moving electrons nor do they have ions
  • Poor conductors of electricity
A

Covalent compounds

20
Q

Involves a metal-metal interaction usually of the same element

A

Metallic bond

21
Q

This bond is formed by the delocalized electron cloud surrounding metal ions

A

Metallic bond

22
Q

The ability of an atom in a molecule to attract shared electrons

A

Electronegativity (EN)

23
Q

4 elements with high EN and usually associated with polar covalent bonds

A
  1. Fluorine (F)
  2. Oxygen (O)
  3. Nitrogen (N)
  4. Chlorine (Cl)
24
Q

Electronegativity difference equal to or greater than this value indicates a polar covalent bond

A

0.5

25
Q

Forces existing between molecules

A

Intermolecular forces of attraction (IFA)

26
Q
  • A charged particle
  • Contains an electrical charge
A

Ion

27
Q

A molecule with two atoms of opposite charges

A

Dipole

28
Q
  • Occurs when the partial positive end of a molecule is attracted to the partial negative end of a neighboring molecule
  • Occurs when polar molecules come very close to one
    another
A

Dipole interaction

29
Q

A special type of dipole interaction existing between the hydrogen atom in a polar bond (usually H-F, H-O and H-N) and an unshared electron pair of an electronegative atom

A

Hydrogen bond

30
Q

The attraction between an ion to a neighboring polar molecule

A

Ion-dipole interactions

31
Q

A polar molecule alters the electron cloud surrounding a nonpolar molecule such that it induces the formation of a
dipole

A

Induced dipole interaction

32
Q

Measure of how easily the surrounding electron cloud can be affected and subsequently distorted

A

Polarizability

33
Q
  • Stands for effective nuclear charge
  • Used to describe the net positive charge experienced by an electron in a multi-electron atom
A

Zeff

34
Q

Increases or Decreases?

Polarizability ___ down the groups in the periodic table because atomic size increases (more electron shell)

A

Increases

35
Q

Increases or Decreases?

Polarizability ___ from left to right across a period in the periodic table because the increasing ___ shrinks atomic size and holds the electrons more tightly

A

Decreases; Zeff

36
Q

More or Less?

Cations are ___ polarizable than their parent atoms because they are smaller; anions are ___ polarizable because they are larger

A

Less; More

37
Q

The weakest intermolecular forces that occur between molecules that come very close to one another

A

Van der Waals interactions

38
Q

Induced dipole interactions and London dispersion forces fall into this category of intermolecular process

A

Van der Waals interactions

39
Q

Higher or Lower?

The stronger the intermolecular force of attraction, the ___ the temperature is needed to break the bond and reach the specific boiling point

A

Higher

40
Q

Higher or Lower?

If the surface area of interaction is more extended than the other, then ___ freezing point is required

A

Lower