Midterms Flashcards
Yellow pigments
Rutin and quercetin
Flavonoid found in yellow flower pigment
“chalcones”
Rutin and and Hesperidin
Vit. P or Permeability factors
Use: tx for capillary bleeding secondary to capillary fragility
Rutin and and Hesperidin
Hesperidin, hesperetin, diosmin
Vitamin P factor or permeability factor
• Tx for capillary bleeding & increased capillary fragility, for HTN
• Rind of unripe citrus fruits
• Necessary for the retention of Vit C
• Tx for symptoms of common colds
Hesperitin, Diosmin, Naringen
Test for Flavonoid Glycosides
Shinoda Test
Powdered extract mixed with a few ml of 95% ethanol,
few drops of conc. HCl and 0.5 g magnesium turnings.
The pink colour was observed.
It indicates the presence of flavonoids. I
Shinoda Test
Test for Alcohol Glycosides:
- Fehlings’s test – brick red ppt
- Nessler’s test – gray ppt
- Tollen’s test – silver mirror ppt
- Schiff’s test – recolorization
V. fragrans
Mexican vanilla
• Best grade
V. plantifolia
Bourbon vanilla
• Blacker in color, covered with vanillin crystals and
possesses coumarin like odor
V. tahitensis
Tahiti vanilla
• Reddish brown in color, odor unpleasant
– unpleasant for flavoring
• Drug that has an aldehydic aglycone as its chief
constituent
• Cured, fully grown fruit
• Const: glucovanillin, glucovanilic alcohol
• Uses: flavoring agent, for perfumery
• Pods – confectionery & perfumery
Vanilla
Flavonoid Glycosides
1- Rue (Ruta graveolens)
2- Milk Thistle (Silybum marianum)
3- Gingko (Gingko biloba)
PHENOL GLYCOSIDES
1- Poison Ivy (Rhus radicans) & Poison Oak (Rhus toxicodendron)
2- Poplar buds (Papulus candicans)
3- Black hawk bark (Viburnum prunifolium)
4- Uva ursi (Arctostaphylos uva ursi)
5- Vanilla (Mexican, bourbon, Tahiti)
Lactone Glycosides/Coumarin Glycosides
1- Melilot (Melilotus officinalis)
2- Cantharides (Cantharis vesicatoria)
3- Santonica – levant (Artemisa cina)
4- Bishop’s weed (Ammi majus)
5- Gentian (Gentiana lutea)
6- Quassia (Picrasma excelsa)
7- Cocculus (Anamirta cocculus)
8- Red sandalwood (Pterocarpus santalinus)
9- Hematoxylon (Hematoxylo n campechianum)
10- Croccus (Crocus sativus)
11- Beet root (Beta vulgaris)
12- Paprika (Capsicum annum)
13- Carrots (Daucus carota)
14- Anata (Bixa orellana)
15- Cudbear (Lecanora acharius)
16- Litmus (Lecanora tartarea)
17- Arnica (Arnica montana)
18- Calamus (Acorus calamus)
Lactone Glycosides
Coumarin Glycosides
FDA banned the use of coumarin and coumarin
containing materials as flavoring agent
Lactone Glycosides/Coumarin Glycosides
• Drug related to coumarin
• From improperly cured leaves and flowering tops of
Melilotus officinales
• is used as an anticoagulant
• D/I: Should not be taken with by person taking Vit. K
Dicumarol
test for Dicumarol
Prothrombin time
Other hydroxylated coumarin derivatives occurring in plants:
• Skimmin – Japanese star anise (Illicium anisatum) – toxic
• anticoagulant
• Aesculin – Horse chesnut tree (Aesculus hippocastanum)
• Fraxin – Fraximus spp
• Scopolin – Atropine belladonna
• Limetin – Citrus spp.
Kedde’s Test
for unsaturated lactone; blue violet
CARBOHYDRATES
❑Composed of Carbon, Hydrogen and Oxygen
❑Monosaccharides as their building blocks.
❑Oligosaccharides
❑Polysaccharides
MONOSACCHARIDES
GLUCOSE
FRUCTOSE
GALACTOSE
RIBOSE
XYLOSE
DISACCHARIDES
SUCROSE
LACTOSE
MALTOSE
POLYSACCHARIDE
❑ HOMOGLYCANS/ HOMOPOLYSACCHARIDES
❑ HETEROGLYCANS/HETEROPOLYSACCHARIDES
HOMOGLYCANS/ HOMOPOLYSACCHARIDES
STARCH
CELLULOSE
GLYCOGEN
INULIN
HETEROGLYCANS/HETEROPOLYSACCHARIDES
GUMS AND MUCILAGE
TEST’S FOR CARBOHYDRATES
MOLISCH’S TEST
FEHLING’S TEST
BENEDICT’S TEST
BARFOED’S TEST
TOLLEN’S TEST
PICRIC ACID TEST
NYLANDER’S TEST
OSAZONE/KOWARSKY TEST
SELIWANOFF’S TEST
KELLER-KILLIANI TEST
MOORE’S TEST
MUCIC ACID TEST
BIAL’S TEST
MOLISCH’S TEST
GENERAL TEST FOR CARBOHYDRATES
α-napthol
Purple / Red
FEHLING’S TEST
REDUCING SUGARS
A. CuSO4
B. K Na Tartrate
Brick red ppt
BENEDICT’S TEST
REDUCING SUGARS
NaOH + CuSO4
Brick red ppt
BARFOED’S TEST
REDUCING SUGARS (MONOSACCHARIDES)
Cupric Acetate + Acetic Acid
Brick red ppt
TOLLEN’S TEST
REDUCING SUGARS (ALDEHYDES)
Silver + Ammonia
Silver Mirror
PICRIC ACID TEST
REDUCING SUGARS
Picric Acid
Mahogany Red
NYLANDER’S TEST
REDUCING SUGARS
Na K Tartrate + K/NaOH + Bi
Brown
OSAZONE/KOWARSKY TEST
MANNOSE
Phenylhydrazine
Yellow ppt (ozone)
SELIWANOFF’S TEST
KETOHEXOSE (FRUCTOSE)
Resorcinol
Red
KELLER-KILLIANI TEST
DEOXYSUGARS (CARDIAC GLYCOSIDES)
Acetic acid, Fe Chloride, Sulfuric Acid
Reddish Brown
MOORE’S TEST
REDUCING SUGARS (GLUCOSE)
Heat with Alkali
Caramel
MUCIC ACID TEST
GALACTOSE
Nitric Acid
Insoluble ppt
BIAL’S TEST
PENTOSES
Resorcinol + Fe
Blue Green
Tragacanth
Astragalus gummifer
Acacia
Acacia Senegal
Ghatti gum
Anogeiesus latifolia
Karaya Gum (3)
Sterculia urens
S. villosa
S. tragacantha
Algin (5)
Macrocystis pyrifera
Laminaria spp.
Ascophyllum spp.
Ecklonia spp.
Nereocystis spp.
Dextran
Leuconostoc mesenteroides
.Agar
Gellidium cartilagineum
Gracillaria confervoides
Carrageenan
Chondrus crispus
Gigartina mamillosa
Danish Agar
Furcellaria fastigiata
Plantago
Plantago psyllium
Psyllium indica
Plantago ovata
Guar gum
Cyamopsis tetragonolubus
Locust beam gum
Ceratonia siliqua
Xanthan gum
Xanthomonas campestris