Methane Lecture 2- Marc Flashcards

1
Q

Define NETs

A

Negative Emission Technologies

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2
Q

name sources of atmospheric methane ( answer lister in rough order of highest to lowest contribution)

A

natural wetlands
fossil fuels
ruminants- ie cows
flooded rice fields
landfills
biomass burning
termites
gas hydrates

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3
Q

what is methanogenesis?

A

Methanogenesis is an anaerobic respiration that generates methane as the final product of metabolism.

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4
Q

what percentage of intake in ruminants is lost as methane

A

2-12

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5
Q

what is the pathway required to methanogenesis

A

polysaccharides
hydrolysis to monomers
acidogenesis to short chain volatile FA
H2, CO2 formate, OR with acetogensis acetate.
both Acetate and h2, co2 undergo methanogenesis to create
CH4 + CO2

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6
Q

What performs methanogenesis

A

Performed by specialised archaea called methanogens (e.g. Methanosarcina, Methanococcus, Methanosaeta)

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7
Q

most archaea are ( two choices)

A

hydrogenotrophic” (CO2 + 4H2 -> CH4 + 2H2O) or acetoclastic (CH3COOH -> CH4 + CO2)

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8
Q

methanogenesis occurs where?

A

Occurs in flooded soils and other environments with a low redox potential (rumen, wastewater treatment plants, lake sediments)

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9
Q

what is methane hydrate?

A

Methane hydrate (also known as clathrate) is a solid where methane is trapped in frozen (crystal) water. Composition is 4CH4·23H2O

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10
Q

where is methane hydrate found?

A

Found mainly along continental shelves (1500-7000 PgC, IPCC 2013)

Also in permafrost (530 PgC)

Stable at low temperature and high pressure

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11
Q

when is CH4 released?

A

if gas hydrates destabilise… i.e if sea level falls.
this is catastrophic, but considered unlikely

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12
Q

what are Aerobic methanotrophs (methane oxidisers)

A

Their key enzyme is the methane monooxygenase
CH4 + O2 -> biomass + ATP

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13
Q

is anaerobic methan oxidation possible?

A

sort of..
Methylomirabilis oxyfera make O2 from NO2-

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14
Q

how much methane is in the atmosphere?

A

542-852 Tg year-1
Biological CH4 oxidation ~800 Tg y-1
Extra 17 Tg year-1 stays in atmosphere

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15
Q

what is methanotrophy?

A

Methanotrophs (sometimes called methanophiles) are prokaryotes that metabolize methane as their source of carbon and chemical energy.

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16
Q

what is the equation for Aerobic methanotrophy (carbon cycle)

A

CH4+ 2O2 –> CO2 + 2H2O

17
Q

what is the equation for anaerobic methanotrophy

A

CH4 + SO (2-/4) OR NO3- –> CO2 + H2S or N2
numbers are end are small- high or low

18
Q

Do hydroelectric dams provide clean energy? what are the downfalls?

A

runoff- water entering reservoir adds decaying plant matter
water level changes- plants grow on banks. then die when level rises
plankton and leafy plants- release gas as they decay
diffusion- gases released from dying plants and soil
degassing- pressure change when water is released frees gases from the water
flood plants + soil- decay occurs after reservoir is first filled

19
Q

Name the sites you might see during thawing permafrost : TKL, ALD, RTS, GTK

A

TKL, thermokarst lakes
ALD, active layer detachment slide;
RTS, retrogressive thaw slump;
GTK, thermal erosion gullies

20
Q

true of false? Countries will rely on NETs to meet Paris agreemetn commitments

A

True

21
Q

Which chemical should be considered in global warming aside from CO2

A

CH4
N2o

22
Q

how is CH4 (methane) mainly produced?

A

naturally

23
Q

true or false? Clean energy tech, such as hydroelectricity, also have negative consequences on ecosystems and the planet

A

true