Metal alloys and phase diagrams Flashcards
DMM1: Materials Deck 5
What is an alloy?
a combination of different materials to metals to improve the material properties of the metal
What are the components of an alloy?
the elements which make up the alloyed metal
What is a phase?
a material with the same:
- structure and atomic arrangment
- composition and properties
throughout
and has a definitive interface with adjacent phases
What is a solution?
a combination of phases where on phase is meixed at an atomic level with aonther
what is a compound?
a combination of phases where the components are chemically bonded to each other
Describe a substitutional solid solution
the solute element replaces solvent atoms in the lattice structure
What are the Hume-Rotheryβs Conditions for unlimited solubility
- Similar sized atoms (less than 15% difference in
radius) - Same crystal structure
- Same number of electrons available for bonding
(valence) - Similar tendency to attract electrons (electronegativity)
What is Solid Solution Strengthening?
substituted solute with different size to the sulvent atoms prevent dislocations moving through the material thus reducing ductility and increasing yeild strength and hardness
Describe and Interstitial solid solution
When solute atoms are much smaller than solvent atoms the solute atoms
can take up positions in gaps between solvent atoms
What is the Alloy constitution of an alloy?
a description of the componds and phases that are present in the alloy
What is Phase structure?
describes how phases are arranged and the alloy constitution
What is a phase diagram
a graph of temperature against percentages mass of solute present.
each phase is labelled and divided from each other
What is a tie line
a horizontal line
drawn through the point
on the phase diagram
representing the alloy of
interest.
extending the line to the boundaries tells the percentage of the solute in each phase
Describe the lever rule
cauculates the proportion of each phase present
π1 =(π_2βπ)/(π_2βπ_1)
or
π2 =(πβπ_1)/(π_2βπ_1)
where P is the amount of phase X is the composition of the alloy and X_1 , X_2 are the composition of the phases
Describe the lever rule geometrically
the length of the tie line between the alloy composition and the opposite phase boundary
divided by the length of the tie line