Manganate equations Flashcards
What is the oxidation state change for Mn in potassium manganate when used as an oxidising agent?
MnO₄⁻ ions are reduced
+7 → +2
-5 change
MnO₄⁻ becomes Mn²⁺
What is the half equation for potassium manganate as an oxidising agent?
MnO₄⁻ ions are reduced
MnO₄⁻ + 5e⁻ + 8H⁺ → Mn²⁺ + 4H₂O
What is the oxidation state change when Fe²⁺ ions are oxidised?
+2 → +3
+1 change
Fe²⁺ becomes Fe³⁺
What is the half equation for the oxidation of Fe²⁺ ions?
Fe²⁺ → Fe³⁺ + e⁻
What is the reaction ratio for the oxidation of Fe²⁺ by potassium manganate?
1MnO₄⁻ : 5Fe²⁺
What is the equation for the oxidation of Fe²⁺ ions by potassium manganate?
MnO₄⁻ + 5Fe²⁺ + 8H⁺ → Mn²⁺ + 5Fe³⁺ +4H₂O
What is the oxidation state change when ethanedioate ions are oxidised?
+3 → +4
+1 change for each carbon
C₂O₄⁻ becomes 2CO₂
What is the half equation for the oxidation of ethanedioate ions?
C₂O₄⁻ → 2CO₂ + 2e⁻
What is the reaction ratio for the oxidation of ethanedioate ions by potassium manganate?
2MnO₄⁻ : 5C₂O₄⁻
What is the equation for the oxidation of ethanedioate ions by potassioum manganate?
2MnO₄⁻ + 5C₂O₄⁻ + 16H⁺ → 2Mn²⁺ + 10CO₂ + 8H₂O
The oxidation of ethanedioate ions by potassium manganate is an example of what kind of reaction?
An autocatalytic reaction
(The reaction produces its own catalyst)
Which product in the reduction of ethanedioate ions by potassium manganate is the catalyst?
Mn²⁺
What are the half equations which explain the autocatalytic reaction of MnO₄⁻ and C₂O₄⁻?
4Mn²⁺ + MnO₄⁻ + 8H⁺ → 5Mn³⁺ + 4H₂O
2Mn³⁺ + C₂O₄⁻ → 2CO₂ + 2Mn²⁺