Free radical substitution Flashcards

1
Q

Free radicals are formed by _______ fission

A

Homolytic

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2
Q

Define a free radical

A

A species with an unpaired electron in its outer shell which makes it highly reactive

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3
Q

What compounds were banned from refrigeration due to their impact on the ozone layer?

A

CFCs
(Chloro-fluoro-carbons)

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4
Q

What is needed to form free radicals in the upper atmosphere

A

UV rays from the sun

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5
Q

How many Initiation steps are there in free radical substitution?

A

1

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6
Q

How many Propagation steps are there in free radical substitution?

A

2

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7
Q

How many Termination steps are there in free radical substitution?

A

3

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8
Q

This is an example of what step in free radical substitution?
Cl₂ → Cl. + Cl.

(Full stop denotes radical)

A

Initiation

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9
Q

This is an example of what step in free radical substitution?
Cl. + CH₄ → HCl + .CH₃

(Full stop denotes radical)

A

Propagation

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10
Q

This is an example of what step in free radical substitution?
F. + O₃ → FO. + O₂

(Full stop denotes radical)

A

Propagation

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11
Q

This is an example of what step in free radical substitution?
Cl. + .CH₃ → CH₃Cl

(Full stop denotes radical)

A

Termination

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12
Q

This is an example of what step in free radical substitution?
F. + F. → F₂

Full stop denotes radical

A

Termination

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