Free radical substitution Flashcards
Free radicals are formed by _______ fission
Homolytic
Define a free radical
A species with an unpaired electron in its outer shell which makes it highly reactive
What compounds were banned from refrigeration due to their impact on the ozone layer?
CFCs
(Chloro-fluoro-carbons)
What is needed to form free radicals in the upper atmosphere
UV rays from the sun
How many Initiation steps are there in free radical substitution?
1
How many Propagation steps are there in free radical substitution?
2
How many Termination steps are there in free radical substitution?
3
This is an example of what step in free radical substitution?
Cl₂ → Cl. + Cl.
(Full stop denotes radical)
Initiation
This is an example of what step in free radical substitution?
Cl. + CH₄ → HCl + .CH₃
(Full stop denotes radical)
Propagation
This is an example of what step in free radical substitution?
F. + O₃ → FO. + O₂
(Full stop denotes radical)
Propagation
This is an example of what step in free radical substitution?
Cl. + .CH₃ → CH₃Cl
(Full stop denotes radical)
Termination
This is an example of what step in free radical substitution?
F. + F. → F₂
Full stop denotes radical
Termination