lipids, water + inorganic ions Flashcards

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1
Q

define what is meant by lipids .

A
  • lipids contain carbon, hydrogen + oxygen atoms - O2 atoms in lipids molecules then in carbohydrates .
  • fats - solid at room temp & oils are liquid .
  • fatty acids contain -COOH group + long hydrocarbon attached = (‘R’ —> ‘RCOOH’.)
  • non-polar = don’t have uneven distribution of charge.
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2
Q

how do triglycerides form?

A
  • condensation reaction between 1 molecule of glycerol (C3H8O3) + 3 fatty acids (3 hydroxyl (OH) which joined through ester bonds.
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3
Q

contrast saturated and unsaturated fatty acids .

A

SATURATED .
- contain single bonds,
- straight chain molecules have many contact points,
- higher melting points —> solid at room temp ,
- found in animal fats

UNSATURATED
- contains C=C double bonds.
- “kinked” molecules have fewer contact points
- lower melting points - liquid at room temperature
- found in plant oils ,

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4
Q

explain the features of triglycerides .

A
  • used as energy stores - energy released when the ester bonds are hydrolysed/ oxidised in respiration.
  • triglycerides clump together into lipid droplets —> hydrophobic tails face inwards + hydrophilic heads face outwards.
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5
Q

relate the structure of triglycerides to their functions .

A
  • high energy: mass ratio = high calorific value from oxidation (energy storage)
  • insoluble hydrocarbon chain = no effect on water potential of cells + used for waterproofing.
  • slow conductor of heat - thermal insulation (adipose tissue: in animals) and thick layers of it “blubber”.
  • less dense than water / buoyancy of aquatic animals .
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6
Q

describe the structure + function of phospholipids .

A
  • glycerol backbone attached to 2 hydrophobic fatty acid tails (face inwards) + 1 hydrophilic polar phosphate heads . ( face outwards)
  • centre of bilyser is hydrophobic - water soluble substances can’t easily pass thru- barrier membrane to those substances .
  • tails can splay outwards = waterproofing .
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7
Q

explain why phospholipids do not dissolve in water .

A
  • tail is hydrophobic but head has “negative” charge - “hydrophillic”
  • when placed in water - arrange themselves on the h2o surface with there down and tails up - form spheres in water - “micelles”
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8
Q

compare phospholipids and triglycerides .

A
  • both have glycerol backbone.
  • both may be attached to a mixture of saturated, monosaturated and polyunsaturated fatty acids .
  • both contain elements ; C, H, O
  • both formed by condensation reactions .
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9
Q

contrast phospholipids and triglycerides.

A

PHOSPHOLIPIDS .
- 2 fatty acids + 1 phosphate group attached
- hydrophilic head and hydrophobic tail
- used primarily in membrane formation .

TRIGLYCERIDES.
- 3 fatty acids attached
- entire molecule is hydrophobic
- used primarily as a storage molecule (oxidation releases energy)

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10
Q

are phospholipids + triglycerides polymers ?

A
  • No, they aren’t made from a small repeating unit.
  • they are macromolecules .
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11
Q

why is water a polar molecule?

A
  • O is more electronegative than H, so attracts the electron density in the covalent bond more strongly.
  • forms O ẟ- (slightly negative charge) + H ẟ+ (slight positive charge.)
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12
Q

describe the process of polarisation regarding water.

A
  • in water - electrons are shared unequally within the bonds that hold a water molecule together
  • oxygen pulls electrons closer towards it and gives oxygen a slight negative charge + hydrogen a slight positive charge .
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13
Q

define the term hydrogen bond .

A
  • weak chemical bonds involving hydrogen atoms . - strong intermolecular force.
  • hydrogen bond forms between slightly negative oxygen atom of one water molecule and slightly positive hydrogen atom on another molecule .
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14
Q

define the meaning of dipole .

A
  • describing a molecule that has a small positive charge in some areas and a small negative charge in others .
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15
Q

state 4 biologically important properties of water.

A

due to polarity + intermolecular H-bonds:

  • metabolite / solvent for chemical reactions in the body
  • high specific heat capacity.
  • high latent heat of vaporisation
    /cohesion between molecules .
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16
Q

describe how specific high capacity may help organisms .

A
  • large amount of energy needed to raise : increase temp of water .
  • all those golden bonds within water good at absorbing energy - add loads to heat h2o
  • “buffers” heat changes = prevents large fluctuations in water temp - keeps temp of aquatic environments stable - organisms not endure extremes of temp.
17
Q

describe how high latent heat of vaporisation may help organisms .

A
  • energy that’s lost from liquid water as it evaporates / lots of energy used to covert water from liquid to gas .
  • provides cooler effect - we feel cooler when we sweat as evaporation of water from our skin’s surface takes a lot of heat energy with it .
18
Q

describe how water is an excellent solvent .

A
  • allows transport substances // so metabolic reactions can occur .
  • because of its polarity and ability to form hydrogen bonds - ions and polar molecules can easily dissolve in it “universal solvent”
    (e.g- hydrophilic molecules dissolve in blood)
19
Q

describe how water is a metabolite .

A
  • acts as a solvent , providing the medium in which most biochemical reactions occurs
  • metabolic in condensation, hydrolysis, photosynthesis, respiration - when water reacts with a chemical to break it into smaller molecules the reaction is described as hydrolysis .
20
Q

explain the difference between cohesion and adhesion.

A
  • adhesion = the force that attracts water molecules to the walls of xylem vessels in a plant
  • cohesion = the way in which molecules “stick” together.
21
Q

describe the cohesion surface tension of water .

A
  • due to hydrogen bonds - formed between partially negative oxygen of one molecule + partially positive hydrogen of another molecule
  • attractions between water molecules allows water to be transported up xylem columns .
  • strong cohesion = surface tension at water - air boundary tension is high
22
Q

describe what is meant by specific heat capacity of a material .

A
  • the energy required to raise 1kg of the material by 1 degree celsius .
23
Q

describe what is meant by the term latent heat is vaporisation .

A
  • the energy that’s lost from liquid water as it evaporates .
24
Q

define the term specific latent heat and the two boundaries that each material contains .

A
  • the amount of energy required to change the state of 1kg of a material without changing its temperature .

—> specific latent heat of fusion : amount of energy needed to melt/ freeze material at melting point

—> specific latent heat of vaporisation : amount of energy needed to boil/condense material at boiling point .

25
Q

what’s the difference between a solute and a solvent ?

A
  • solute = substance that is being dissolved .
  • solvent = substance in which the solute dissolves in.
26
Q

why are hydrogen bonds weaker than strong covalent bonds ?

A
  • constantly breaking + reforming but when large no. present they form strong structure
  • covalent bonds - stronger bonds as loads of energy needed to split hydrogen and oxygen atoms apart .
27
Q

explain the role of hydrogen ions in the body .

A
  • important for respiration + photosynthesis reactions and influences pH if a cell by increasing acidity
  • H+ ions interact with H-bonds + ionic bonds in tertiary structure of proteins cause to denature .
28
Q

explain role of iron ions in body .

A

Fe2+ bonds to porphyrin ring to form haem group in haemoglobin .
haem group binding site to transport 1 molecule of O2 around body in bloodstream .

29
Q

explain the role of sodium ions in the body .

A
  • involved in co-transport for absorption of glucose + amino acids in lumen in gut
  • involved in propagation of action potentials in neutrons
30
Q

explain the role of phosphate ions in the body .

A
  • synthesise biological molecules like nucleic acids/ phospholipids .
  • DNA , ATP
31
Q

describe the role of calcium ions in the body .

A
  • needed for transmission of action potentials , the formation of bone, release of insulin from pancreas and as enzyme cofactor
32
Q

describe role of potassium ions in the body .

A
  • generation of action potentials, muscle contraction , maintaining blood pressure and for activating photosynthesising enzymes in plants .
33
Q

describe the role of ammonium ions .

A
  • important for nitrogen cycle - absorbed by plants and incorporated into amino acids for protein synthesis.
34
Q

describe role of hydrogen carbonate ions in the body

A
  • maintains constant pH in the blood by acting as a buffer .
35
Q

describe role of chloride ions in the body .

A
  • maintains constant pH in blood through process of ‘chloride shift’ + acts as cofactor for enzyme amylase .
36
Q

describe role of hydroxide ion in the body

A
  • changes the pH of the cell by making the area more alkaline .
37
Q

Explain why triglycerides and phospholipids are soluble in ethanol.

A
  • alcohols such as ethanol are non polar . although ethanol has small polar region, the bulk of it is made up of non polar region.
  • non-polar substances able to mix together, so triglycerides and phospholipids able to dissolve in alcohols such as ethanol