lipids, water + inorganic ions Flashcards
define what is meant by lipids .
- lipids contain carbon, hydrogen + oxygen atoms - O2 atoms in lipids molecules then in carbohydrates .
- fats - solid at room temp & oils are liquid .
- fatty acids contain -COOH group + long hydrocarbon attached = (‘R’ —> ‘RCOOH’.)
- non-polar = don’t have uneven distribution of charge.
how do triglycerides form?
- condensation reaction between 1 molecule of glycerol (C3H8O3) + 3 fatty acids (3 hydroxyl (OH) which joined through ester bonds.
contrast saturated and unsaturated fatty acids .
SATURATED .
- contain single bonds,
- straight chain molecules have many contact points,
- higher melting points —> solid at room temp ,
- found in animal fats
UNSATURATED
- contains C=C double bonds.
- “kinked” molecules have fewer contact points
- lower melting points - liquid at room temperature
- found in plant oils ,
explain the features of triglycerides .
- used as energy stores - energy released when the ester bonds are hydrolysed/ oxidised in respiration.
- triglycerides clump together into lipid droplets —> hydrophobic tails face inwards + hydrophilic heads face outwards.
relate the structure of triglycerides to their functions .
- high energy: mass ratio = high calorific value from oxidation (energy storage)
- insoluble hydrocarbon chain = no effect on water potential of cells + used for waterproofing.
- slow conductor of heat - thermal insulation (adipose tissue: in animals) and thick layers of it “blubber”.
- less dense than water / buoyancy of aquatic animals .
describe the structure + function of phospholipids .
- glycerol backbone attached to 2 hydrophobic fatty acid tails (face inwards) + 1 hydrophilic polar phosphate heads . ( face outwards)
- centre of bilyser is hydrophobic - water soluble substances can’t easily pass thru- barrier membrane to those substances .
- tails can splay outwards = waterproofing .
explain why phospholipids do not dissolve in water .
- tail is hydrophobic but head has “negative” charge - “hydrophillic”
- when placed in water - arrange themselves on the h2o surface with there down and tails up - form spheres in water - “micelles”
compare phospholipids and triglycerides .
- both have glycerol backbone.
- both may be attached to a mixture of saturated, monosaturated and polyunsaturated fatty acids .
- both contain elements ; C, H, O
- both formed by condensation reactions .
contrast phospholipids and triglycerides.
PHOSPHOLIPIDS .
- 2 fatty acids + 1 phosphate group attached
- hydrophilic head and hydrophobic tail
- used primarily in membrane formation .
TRIGLYCERIDES.
- 3 fatty acids attached
- entire molecule is hydrophobic
- used primarily as a storage molecule (oxidation releases energy)
are phospholipids + triglycerides polymers ?
- No, they aren’t made from a small repeating unit.
- they are macromolecules .
why is water a polar molecule?
- O is more electronegative than H, so attracts the electron density in the covalent bond more strongly.
- forms O ẟ- (slightly negative charge) + H ẟ+ (slight positive charge.)
describe the process of polarisation regarding water.
- in water - electrons are shared unequally within the bonds that hold a water molecule together
- oxygen pulls electrons closer towards it and gives oxygen a slight negative charge + hydrogen a slight positive charge .
define the term hydrogen bond .
- weak chemical bonds involving hydrogen atoms . - strong intermolecular force.
- hydrogen bond forms between slightly negative oxygen atom of one water molecule and slightly positive hydrogen atom on another molecule .
define the meaning of dipole .
- describing a molecule that has a small positive charge in some areas and a small negative charge in others .
state 4 biologically important properties of water.
due to polarity + intermolecular H-bonds:
- metabolite / solvent for chemical reactions in the body
- high specific heat capacity.
- high latent heat of vaporisation
/cohesion between molecules .