LIPIDS IN ANIMAL NUTRITION Flashcards
are long chain organic acids having usually from 4 to 30 carbon atoms, they have a single carboxyl group and a long non-polar hydrocarbon tail which gives most lipids their hydrophobic and oily or greasy nature
Fatty Acids
They are esters of fatty acid with trihydric alcohol glycerol. The most abundant are the fats and the less abundant are waxes.
Simple lipids
Both have the same general structure and chemical properties but different physical
characteristics.
Fats and Oils
Three fatty acid:
linoleic, linolenic and arachidonic acids
Fats are hydrolysed to glycerol and fatty acid by the enzymes (lipases) and by alkali in the presence of water.
Hydrolysis
Is defined as the milligrams of potassium hydroxide required to saponify 1 gram of fat.
Saponification number
The unsaturated glycerides of fat may be hydrogenated by treatment with hydrogen in the presence of nickel catalyst to form cooking fats. Oleic acid is hydrogenated to stearic acid.
Hydrogenation
This is defined as the percent of iodine absorbed by the fat or the grams of iodine absorbed by 100 grams of fat.
Iodine number
The glycerides of fats containing hydroxylated fatty acids react with acetic anhydride and other acylating agents to form the corresponding esters.
Acetylation
is defined as the milligram of KOH required to combine with the acetic acid liberated by the saponification of one gram of acetylated fat.
Acetyl number
It is the milligrams of KOH required to neutralize the free fatty acids present in 1 gram of fat.
Acid number
It is defined as the number of me. of decinormal
alkali required to neutralize the steam volatile fatty acid from 5 g of fat.
Reichert- Meissl number (R.M. Value)
It is the number of milliliters of 0.1 N KOH required to neutralize the insoluble fatty acids obtained from 5 gram of fat.
Polenske Number
It is caused by the micro-organism in the fat in which short chain fatty acids are hydrolysed into malodourous fatty acids. But nutritive value of fat in
hydrolytic rancidity remains same.
Hydrolytic rancidity
Oils containing highly unsaturated F.A. are spontaneously oxidized into short chain F.A.
Oxidative rancidity