Lipids Flashcards
State the elements present in lipids (and the additional element needed to make phospholipids)
Carbon, Hydrogen, Oxygen + Phosphor
Define the term “macromolecule”.
Complex molecules that have a relatively large molecular mass.
State the 3 categories of lipids (or lipid derived molecules).
- Triglycerides
- Phospholipids
- Sterols
Draw a labelled diagram showing the basic structure of a triglyceride. (Draw it on a piece of paper and check)
- Three fatty acid tails attached to one glycerol molecule
- They are synthesised by the formation of an ester bond.
State the components of a triglyceride.
Three fatty acid tails and a glycerol head.
State the difference between saturated, monounsaturated and polyunsaturated and how being one the other can change their properties.
saturated: no carbon-carbon double bonds between carbon atoms in their hydrocarbon tails. This means they can pack together as they are straight and are solid at RT.
monounsaturated/ Polyunsaturated: have at least one carbon double bond between carbon atoms. This causes them to bend or kink, meaning that cannot pack close together. This makes them liquid at RT. Monousaturated fatty acids have only one double bond.
Polyunsaturated fatty acids are the healthiest because they cannot be stored as solid fat, due to them being so bendy.
Explain why saturated triglycerides tend to be solid (fats) at room temperature whereas unsaturated triglycerides tend to be liquid (oils).
Saturated triglycerides don’t have kinks so they can pack together tightly, meaning that there are more intermolecular interaction between the fatty acid chains. Therefore, it takes more energy to separate them.
Unsaturated triglycerides do have kinks so they bend and cannot pack closely together. Fewer intermolecular interactions. Takes less energy.
Describe and explain how the melting point of a triglyceride would correlate with the length of the fatty acids it contained.
The longer the fatty acid chain the higher the melting point of the triglyceride. This is because longer fatty acids chain have a greater surface area for intermolecular interactions between them. This means that it takes more energy to break the chains apart, because there are a lot moreintermolecular interactions.
(Also, longer chain means more covalent bonds which are very hard to break).
State the difference between the triglycerides found in non-fish animals and those in plants and fish.
Plants have unsaturated triglycerides and animals have saturated triglycerides.
Draw a labelled diagram showing the basic structure of a phospholipid.
They have the same structure as a triglyceride expect on of their fatty acid tails is replaced by a phosphate group which is on the opposite side of the glycerol to the other two fatty acids. One of their fatty acids is saturated and the other is unsaturated.
State the property that each end of the phospholipid has.
The phosphate group is hydrophilic - attracts and readily interacts with water molecules
Fatty acid tails are non-polar hydrophobic - they repel water and are insoluable in it.
Draw a diagram to show how a triglyceride is formed and broken down.
Ester bonds are formed by a condensation reaction where a water molecule is released - esterification. The hydroxyl groups from the fatty acid tails and the glycerol interact to produce three water molecules and three ester bonds. Esterfication is another example of a condensation reaction.
When ester bonds are broken a hydrolysis reaction where a water molecule is used up the tricglyceride and the fatty acid tails break apart.
Name the bond that holds the building blocks of a triglyceride together.
Ester bond
State the number of water molecules produced in the production of one triglyceride.
Three water molecules
State the products of digestion of a triglyceride (include partial digestion) and state what would happen to the pH of the solution (and why).
Products of digestion: free fatty acids and monoglycerides.
The PH of the solution would go down (more acidic) because you have free fatty acids (which are acids).