Lipids 2 Flashcards
Simple lipids are … And …
Triacylglycerol
Waxes
Wax composition + examples
Monohydric alcohol+ fatty acid
Bee wax»_space; palmitic acid C16+ myricyl alcohol C30
Cholesteryl ester» lanolin(animal fur+ skin enhancement)
Vitamin A (retinol)
Vitamin D (calciferol)
Triacyl glycerols composition
Glycerol general + bonded to..
3 fatty acids+ 1 glycerol
Glycerol> odourless, colourless,sweet,miscible in water
R1> saturated fatty acid
R2>unsaturated
R3>either
Physical properties of TAGs
Yellow colour due to cartenoids
Colourless and odourless
Insoluble in water
Soluble in fats
Chemical properties of simple lipids
Rancidity
Hydrogenation/hardening (from USFA to SFA)margarine
Rancidity
What
Types
Development of bad odor in fats due to exposure of high temperature moisture ,humidity and metals that act as catalysts.
Hydrolytic» butter
Oxidative» oils
Difference bet hydrolytic and oxidative
Hydrolytic» high temp release of short chain fatty acids due to bond breaking by lipase enzyme
Oxidative»oxidation of USFA to produce peroxides causing the chains to be broken, bad odour and bitter taste
Protecting from rancidity
Addition of antioxidants like vitamin E and phenols, decreasing rate of rancidity and protect from oxidation
Compound lipids classification
Acc to Alcohol
Phosphoglycerides
Sphingomylein
Phosphoglycerides are broken down by…
Phospholipases
Parent group of phophoglycerides
Phosphatidic acid
Glycerol+ saturated+ unsaturated+ phosphoric acid
Lecithin
Phosphatidic+ choline
Cell membrane of brain/liver/lung
Lipotropic factor, preventing fatty liver
Forms cholesterol ester
Cephalin
Phosphatidic acid+ ethanol amine
Phosphatydlserine
Phosphatidic acid+ serine
Phosphatdyl glycerol
Phosphatidic acid+ glycerol