lipids Flashcards

1
Q

elements in lipids?

A

C H & O

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2
Q

what are fats?

A

solid lipids at room temp

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3
Q

what are oils?

A

liquid lipids at room temp

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4
Q

are lipids polar?

A

no - electrons in outer orbitals that form bonds are more evenly distributed than in polar molecules

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5
Q

why are lipids non-polar?

A

electrons in outer orbitals that form bonds are more distributed than in polar molecules

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6
Q

“lipid” definition

A

large complex macromolecules built from repeating units made of C H & O

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7
Q

“macromolecule” definition

A

large complex molecules made form repeating units

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8
Q

triglyceride structure

A

1 glycerol + 3 fatty acids

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9
Q

what group is glycerol?

A

alcohols

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10
Q

what group are fatty acids?

A

carboxylic acids

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11
Q

what are fatty acids made of?

A

carboxyl group + hydrocarbon chain

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12
Q

what reaction is the formation of triglyceride?

A

condensation reaction: esterification

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13
Q

what bonds between glycerol & fatty acids are formed and how?

A

ester bonds ; hydroxyl groups on both react removing water (1H from glycerol + OH from fatty acids)

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14
Q

triglyceride general formula?

A

CH2 O CH2 (CH2)n CH3

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15
Q

“saturated” meaning

A

no double bonds between carbons bc all carbons form max bonds with hydrogen

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16
Q

“unsaturated” meaning

A

double bonds present between some carbon atoms bc not all have max hydrogen bonds

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17
Q

“monounsaturated” definition

A

only one double bond present between carbon atoms

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18
Q

“polyunsaturated” definition

A

2+ double bonds between carbon atoms

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19
Q

why are oils liquid at room temp?

A
  • double bonds = molecule kinks and bends
  • can’t pack close together
  • liquid rather than solid = oils not fats
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20
Q

triglycerides in plants?

A

unsaturated + healthier for human diet than saturated

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21
Q

what can excess saturated fat in diet lead to?

A

CHD / obesity = strain on heart

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22
Q

elements in phospholipids?

23
Q

“phospholipids” definition

A

modified triglycerides containing C H O & P

24
Q

where are phosphate ions found?

A

cytoplasm of every cell

25
phosphate ions characteristics?
PO4 3- have extra electrons = neg charge = soluble in water
26
phosphate ion charge?
PO4 3-
27
phospholipid structure?
one of triglyceride fatty acid chains —> phosphate group
28
are phospholipid heads non-polar?
**NO - THEY’RE CHARGED**
29
what hydro are phospholipid heads?
hydrophilic ; charged = interact with polar water
30
are phospholipid heads polar?
no
31
are phospholipid tails polar?
no ; non-polar
32
what hydro are phospholipid tails? why
hydrophobic = repelled by water
33
what do phospholipid tails interact with?
mix with fats not water
34
what do phospholipid heads interact with?
water
35
how do phospholipids interact with water?
- layer on the surface - heads in water and tails sticking out = surface active agents (surfactants)
36
phospholipid bilayer structure?
- tails pointed inwards away from water - heads outside interacting with water
37
what do phospholipids help form in cells?
cell membranes
38
how are phospholipids useful in cells?
- cell membranes - separate aqueous cell environment OUTSIDE from aqueous cytosol IN cells
39
what group are sterols?
steroid alcohols
40
are sterols lipids?
yes but NOT oils or fats
41
sterol structure?
complex alc molecules - 4 carbon ring structure - hydroxyl group on one end
42
sterol characteristics?
dual hydrophilic (polar hydroxyl group) & hydrophobic (rest of molecule)
43
where is cholesterol made?
in the liver & intestines
44
what is cholesterol used for?
positioned between phospholipids in bilayer with hydroxyl groups at periphery of membrane
45
why is cholesterol useful?
between phospholipids = stability to membrane +regulates fluidity by keeping fluid at low temps + not too fluid at high temps
46
what is made from cholesterol
- vitamin D - steroid hormones - bile
47
biological roles of lipids?
- membrane formation + hydrophobic barriers - hormone production - electrical insulation for impulse transmission - waterproofing - long term energy storage
48
where are lipids stored in the body?
under the skin and around vital organs
49
benefits of lipids under the skin?
- thermal insulation eg. penguins, seals - cushioning (protects vital organs eg. heart kidney) - buoyancy in aquatic animals (whales)
50
what is the test for lipids called?
emulsion test
51
describe the emulsion test?
1. mix sample with ethanol 2. mix this with water and shake 3. white emulsion forms if lipid present
52
positive emulsion test result?
white emulsion layer on top
53
negative emulsion test result?
solution remains clear