carbohydrates Flashcards

1
Q

elements in carbohydrates?

A

C H & O

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2
Q

general formula of carbs?

A

Cn(H2O)n

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3
Q

“monosaccharide” definition

A

single sugar / carb / saccharide unit

glucose , fructose , ribose

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4
Q

“disaccharide” definition

A

when 2 monosaccharides join together

lactose , sucrose (fructose + glucose)

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5
Q

“polysaccharide” definition

A

when 2+ monosaccharides join together to form a polymer

glycogen , cellulose , starch

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6
Q

monosaccharide examples:

A
  • glucose
  • fructose
  • ribose
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7
Q

glucose formula?

A

C6H12O6

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8
Q

what structure is glucose?

A

hexose monosaccharide (6 carbon hexose sugar)

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9
Q

alpha glucose structure

A

carbon 1 to 6 up to down bonds:

H OH
H OH
OH H
H OH
CH2OH H
O

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10
Q

beta glucose structure

A

carbon 1 to 6 up to down bonds:

OH H
H OH
OH H
H OH
CH2OH H
O

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11
Q

is glucose polar and soluble and why?

A

polar + soluble in water bc H bonds between hydroxyl groups and water molecules

soluble = glucose dissolved in cytoplasm of the cell

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12
Q

glucose condensation reaction?

A

1,4 glycosidic bond eliminating C1 OH and C4 OH + side product H2O

glucose —> disaccharide maltose

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13
Q

hexose monosaccharide examples?

A
  • glucose
  • fructose (fruit)
  • galactose
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14
Q

glucose polymer?

A

glycogen

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15
Q

maltose monomers?

A

a glucose + a glucose

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16
Q

sucrose monomers?

A

a glucose + fructose

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17
Q

lactose monomers?

A

b glucose + galactose

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18
Q

“starch” ?

A

polysaccharide of a glucoses - chemical store of energy

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19
Q

two types of starch molecules?

A
  • amylose
  • amylopectin
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20
Q

amylose structure + characteristics?

A
  • 1,4 glycosidic bonds
  • bond angle = long glucose chain helix twist (stable by h bonds)
  • more compact + less soluble
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21
Q

benefits of amylose structure?

A
  • more compact + less soluble
22
Q

amylopectin structure + characteristics?

A
  • 1,4 glycosidic bonds a glucose molecules
  • 1,6 glycosidic bonds every 25 glu molecules (condensation reactions)
  • branched structure
  • insoluble
23
Q

energy store in plants?

A

starch (amylose amylopectin)

24
Q

energy store in animals?

25
benefits of glycogen as an energy store?
- more branched than amylopectin = more compact + takes less storage space bc cooling + branching - branching = free ends for more glucose added b removed =quick process of storing / releasing glu molecules for cells
26
key glucose + amylopectin properties?
- insoluble - branched - compact
27
why is branching / coiling good?
- compact = less space used - branching = free ends = removal or additional of glu molecules = quick release / store of glucose
28
“respiration”
process where biochemical energy in nutrients is converted into useable energy for organisms
29
how does starch/glycogen release glucose?
hydrolysis breaking glycosidic bonds
30
why can’t b glucose join like a glucose?
hydroxyl groups on C1 C4 too far away
31
how can b glucose combine?
- flip one b glucose upside down - unable to coil or branch - straight chain “cellulose”
32
cellulose monomers?
b glucose + b glucose
33
disaccharide examples?
- sucrose - maltose
34
polysaccharide examples?
- glycogen - cellulose - starch
35
what does cellulose make up in humans?
cellulose —> microfibrils —> macrofibrils —> fibres —> cell walls (strong + insoluble)
36
why is cellulose important for the diet?
hard to break down but forms fibre for healthy digestive system
37
what are reducing sugars?
donate electrons / reduce the other molecule
38
reducing sugar examples
ALL monosaccharides and SOME disaccharides (maltose lactose)
39
non-reducing sugar examples
sucrose
40
reducing sugar test name
Benedict’s test
41
explain the reducing sugars test
Benedict’s test 1. place sample in boiling tube 2. add equal volume of Benedict’s reagent 3. heat mixture gently in water bath for 5 mins
42
what is Benedict’s reagent?
alkaline copper II sulfate solution
43
Benedict’s test results?
- red Cu2 react w copper ions = adds electrons to blue Cu2+ ions —> reduced to brick red Cu+ ions - red precipitate
44
why is a red precipitate formed in Benedict’s yes for reducing sugars?
- sugars reduce Cu2+ blue ions —> red Cu+ ions - red precipitate more reducing sugars = more red precipitate
45
reducing sugars test effect on non reducing:
- remains blue (blue —> green —> yellow —> orange —> red) = neg result
46
how can sucrose give a positive result?
boil sucrose (DISACCHARIDE) in dilute HCl = hydrolysed to glucose or fructose (MONOSACCHARIDES) then gives pos result
47
starch test name?
iodine test
48
describe the starch test?
mix few drops of iodine dissolved in potassium iodide with solution yellow —> blue / black
49
starch test results?
yellow / brown —> blue / black
50
what are reagent strips used for?
to test for reducing sugars
51
benefits of reagent strips?
use of a colour chart showing sugar concentration