LIPIDS Flashcards
Refers to a collection of organic molecules of
varying chemical composition
LIPIDS
4 main groups LIPIDS
o Fatty Acids (Saturated and Unsaturated)
o Glycerides (Glycerol-containing Lipids)
o Nonglyceride Lipids (Sphingolipids, Steroids,
Wax)
o Complex Lipids (Lipoproteins)
lipid structure CPGF
Choline
Phosphate
Glycerol
Fatty acids
o Esters of fatty acids with various alcohol
o Fats and waxes
Simple lipids
o Esters of fatty acids containing groups in
addition to an alcohol and a fatty acid
o Phospholipids, glycolipids and other complex
lipids like sulfolipids and amino lipids
Compound lipids
o derived by hydrolysis from compound and
simple lipids
o alcohols, mono- and diglycerides, carotenoids,
steroids, and terpenes
Derived lipids
- Waxes
LIPIDS WITH FATTY ACIDS
- Fats and oils (triglycerides)
LIPIDS WITH FATTY ACIDS
- Phospholipids
LIPIDS WITH FATTY ACIDS
- Sphingolipids
LIPIDS WITH FATTY ACIDS
- Cholesterol
LIPIDS WITHOUT FATTY ACIDS
- Bile Acids
LIPIDS WITHOUT FATTY ACIDS
- Steroids
LIPIDS WITHOUT FATTY ACIDS
fatty acid composition
Polar End - hydrophilic
Non-polar End- Hydrophobic
fatty acid with long chain
more than 12 carbons
fatty acid with medium chain
6-10 carbons
fatty acid with short chain
less than 6 carbons
18:2n-6 (PUFA CODE)
number of carbons
number of double bonds
number of carbons up to the first double bond
Oleic Acid
Omega 9
monounsaturated
Linoleic Acid
Omega 6
polyunsaturated
Alpha-linolenic acid (ALA)
Omega 3
polyunsaturated
- Omega-3:
o body can make some _____ and ____ from ALA
EPA - eicosapentaenoic acid
DHA - docosahexaenoic acid
Examples of omega-6 PUFA
Linoleic acid
arachidonic acid
- H’s on same side of the double bond
- fold into a U-like formation
- naturally occurring
cis- fatty acids
- H’s on the opposite side of the double bond
- occur in partially hydrogenated food
trans- fatty acids
C-C BOND OF SATURATED FATTY ACID
single bond
C-C BOND OF UNSATURATED FATTY ACID
at least 1 double bond
Hydrocarbon
chains are
characteristic of
what group of
hydrocarbons for SAturated fatty acid?
alkanes
Hydrocarbon
chains are
characteristic of
what group of
hydrocarbons for unsaturated fatty acid?
alkenes
Saturated fatty acid
“Shape” of
Hydrocarbon
chain
Linear, Fully extended
“Shape” of
Hydrocarbon
chain (unsaturated)
Bend in carbon
chain at site of C-C double bond
Physical state at
room temperature of Saturated Fatty acid
solid
Physical state at
room temperature of unsaturated fatty acid
Liquid
Melting point of saturated fatty acid
Higher
Melting point of unsaturated fatty acid
Lower
fatty acids that canno tbe prepared by the body
obtained from diet
Essential fatty acid
fatty acids that can be synthesiszed by our body
not required from diet
Non-essential fatty acid
Examples of essential fatty acid
linoleic acid
linolenic acid
arachidonic acid
examples of non-essential fatty acids
palmitic acid
stearic acid
Fatty acids react with alcohols to form esters and
water
ESTERIFICATION
ester are products of deyhdration of a _________ and an _________
carboxylic acid
alcohol
o Producing fatty acids from esters
o Opposite of esterification
ACID HYDROLYSIS
o hydrolysis of an ester with a strong base
o Is the alkaline hydrolysis of the fatty acid esters
SAPONIFICATION
SAPONIFICATION product, an ionized salt, is a
soap Have a long ________hydrocarbon tail
and a _______ charged terminus (the
carboxylate terminus)
uncharged
negatively
REACTION AT THE DOUBLE BOND –
UNSATURATED FATTY ACIDS
Hydrogenation
Partial Hydrogenation
polyunsaturated vegetable oils into saturated
solid fats
Hydrogenation
vegetable oils are
converted into solid form
Partial Hydrogenation
FAtty acids carry more energy per carbon because they are more _____
reduced
Fatty acids carry less water per gram because they are ____________
nonpolar
short term energy need
glucose
glycogen
long term energy needs
fats
Are lipid esters that contain the glycerol molecule
and fatty acids
glycerides
nonionic and nonpolar
Neutral Glycerides
have polar region, the
phosphoryl group, in addition to the nonpolar
fatty acid tails
Phosphoglycerides
Produce after the esterification of glycerol with a
fatty acid
Neutral Glycerides
Neutral Glycerides most important and main storage form of lipids in
man, what cell?
adipocytes
primary functions of neutral glycerides
store energy
Triglyceride structure
Glycerol + 3 fatty acids
Triglyceride is _ kcals per gram
9
food sources of triglycerides
fats and oils
omega-3 fatty acids
omega-6 fatty acids
A mixture of triglycerides containing high
proportion of long-chain, saturated fatty acids
* Animals – generally solids
FAT
Liquid fat
* Contain high proportion of unsaturated fatty
acids and saturated fatty acids
* Plants or Fish – usually liquids
OIL