Lipids Flashcards
principal component of carnauba wax (Brazilian wax palm)
myricyl cerotate
principal component of
spermaceti
cetyl palmitate
Formed when the hydroxyl groups of glycerol react with the carboxyl groups of fatty acids
triglycerides
double bonds in unsaturated fatty acids react with H2 in the presence of a Ni or Pt catalyst.
hydrogenation
ester bonds are split by water in the presence of an acid, a base, or an enzyme.
hydrolysis
Converts double bonds to single bonds.
hydrogenation
majority of the unsaturated fatty acids are: cis or trans?
cis
formed during hydrogenation when cis double bonds are converted to trans double bonds
trans fatty acids
trans fatty acids raise
____ cholesterol
lowers
____ cholesterol
- LDL or bad cholesterol
- HDL -gets rid of excess cholester
Triacylglycerols split into glycerol and three fatty acids.
hydrolysis
The basic hydrolysis of fat and oils produces
soap or in the process of saponification
the reaction of a fat with a strong base.
saponification
gives softer soaps
KOH
A sodium or potassium salt of a fatty acid.
soap
The most abundant lipids in cell membranes
glycerophospholipids
glycerophospholipids are composed of
glycerol
two fatty acids
phosphate amino alcohol
Glycerophospholipids Are: polar or non-polar
polar
polar amino alcohols
choline
serine
ethanolamine
Abundant in brain and nerve tissues
lecithin and cephalin
simplest sphingolipids
ceramide
cellular signalling
ceramide
a sphingolipid found in membrane of nerve cells
sphingomyelinw
lipid-rich membrane sheath that surrounds the axons of nerve cells; High content of sphingomyelins
myelin
contain monosaccharides bonded to the –OH of sphingosine by a glycosidic bond.
glycosphingolipids
glycosphingolipids are composed of
galactose or glucose
similar to cerebrosides, but contain two or more monosaccharides.
gangliosides
a cerebroside with galactose or glucose.
glycospingolipids
Act as receptor for hormones and
viruses.
gangliosides
GM2 is a ganglioside; accumulates in
Tay-Sachs disease
Blockage in the catabolism of ganglioside
Tay Sachs Disease
Tay sachs disease is a Lack of the enzyme
hexosaminidase A
A steroid nucleus consists of
3 cyclohexane rings. • 1 cyclopentane ring
the most abundant steroid in the body
cholesterol
highest cholesterol content
liver
steroids in plants
phytosterols
synthesized in the liver from cholesterol
bile salts
Combine lipids with proteins and phospholipids.
lipoproteins
chemical messengers in cells.
• produced from cholesterol.
steroid hormones
steroid hormones include
androgens and estrogens
prepares uterus for fertilized egg
progesterone
contraceptive
norethindrone
produced by the adrenal glands located on the
top of each kidney.
adrenal corticosteroids
regulates electrolytes and water balance by the kidneys.
aldosterone
glucocorticoid, which increases blood glucose level and stimulates the synthesis of glycogen in the liver.
cortisone
derivatives of testosterone.
• used illegally to increase muscle mass.
anabolic steroids
growth and differentiation of tissue and in good vision
vitamin
A
calcium absorption & retention in bones
vitamin
D
Serves as antioxidant; may be necessary for reproduction in humans
vitamin
Vitamin E
tocopherol
Regulatory function in blood clotting
vitamin
K
Deficiency of Vit D
rickets
Powerful antioxidant – good reducing
agent
Remove free radicals (high degree of reactivity); play a part in the devt of cancer & in aging process.
• Prevent biomolecules from degradation.
Vitamin E (a-tocopherol)
determine the
exact form of vitamin K
number of isoprene units
examples of anabolic steroids
methandienone
oxandrolone
nandrolone
stanozolol