Lipid Structure and Function Flashcards
Amphipathic Properties of Lipid Bilayer
polar heads on outsides (hydrophilic), and fatty acid tails on the insides (hydrophobic)
Phospholipid Structure
contain a phosphate and an alcohol that makeup the head group and are joined to hydrophobic fatty acid tail by a phosphodiester bond
Saturated Fatty Acids
all single bonds, greater stability
Unsaturated Fatty Acids
at least one double bond
Phosphoglycerides
aka glycerophospholipids
type of phospholipid that contains a glycerol backbone, bonded by ester linkages to 2 fatty acids and by a phosphodiester linkage to a polar head
Sphingolipids
have a sphingosine or phingoid backbone, long chain fatty acid tails and polar head groups
can be either a phospholipid or a glycolipid
Waxes
esters of long chain fatty acids with long chain alcohols that are used for protection
Steroids
metabolic derivatives of terpenes and are non polar and very different from most other lipids, have 4 cycloalane rings fused together
Cholesterol
type of steroid, common in phospholipid bilayer and is responsible for mediating membrane fluidity
Protaglandins
20 carbon molecules that are unsaturated carboxylic acids derived from arachidonic acid and contain a 5 carbon ring, act as paracrine and autocrine signalling molecules
Triglycerol Structure
3 fatty acids bonded by ester linkages to glycerol, they are nonpolar and hydrophobic
Free Fatty Acids
unesterified with a free carboxylate group and circulate in blood bound to albumin
Saponification
the ester hydrolysis of triglycergides using a strong base resulting in the cleavage of the fatty acid leaving the sodium salt and glycerol