Carbohydrate Structure and Function Flashcards

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1
Q

3-C Sugar

A

Triose

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2
Q

4-C Sugar

A

Tetrose

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3
Q

Sugars with Aldehydes as most Oxidized Group

A

Aldose

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4
Q

Sugars with Ketones as most Oxidized Group

A

Ketose

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5
Q

D-Sugars

A

the highest numbered chiral carbon with the -OH group on the right (in a Fischer Projection)

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6
Q

L-Sugars

A

the highest numbered chiral carbon with the -OH group on the left (in a Fischer Projection)

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7
Q

L and D of the same sugars are:

A

Enantiomers

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8
Q

Diastereomers

A

differ at at least one, but not all, chiral carbons

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9
Q

Epimers

A

Differ at exactly one chiral carbon

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10
Q

Anomers

A

are a subtype of epimers that differ at the anomeric carbon

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11
Q

Anomeric Carbon

A

the new chiral centre formed in ring closure, it was the carbon containing the carbonyl in the straight chain form

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12
Q

Alpha Anomers

A

have the -OH on the anomeric carbon trans to the free -CH2OH group

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13
Q

Beta Anomers

A

have the -OH on the anomeric carbon cis to the free CH2OH group

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14
Q

Mutarotation

A

one anomeric form switches to the form and the straight chain form is the intermediate

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15
Q

What is it

A

D- Fructose

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16
Q

What is it?

A

D-Glucose

17
Q

What is it?

A

D- Mannose

18
Q

What is it?

A

D-Galactose

19
Q

Glycoside Formation

A

The basis for building complex carbohydrates and requires the anomeric carbon to link to another sugar

20
Q

Sucrose

A

Glucose-alpha-1,2-fructose

21
Q

Lactose

A

Galactose-beta-1,4-glucose

22
Q

Maltose

A

glucose-alpha-1,4-glucose

23
Q

Deoxy Sugars

A

-H group replacing an -OH group

24
Q

Cellulose

A

main structural componenet of plant cell walls; main source of fiber in human diet

25
Q

Starches

A

amylose and amylopectin

main energy storage forms for plants

26
Q

Glycogen

A

a major energy storage form for animals

27
Q

When Swtiching from a Fisher Projection to a Haworth diagram

A

groups on the right point down, groups on the left point up