Lecture 5 Flashcards
The most abundant chemical elements in the continental crust
Dominantly oxygen and silicon
Differentiation process causes _____ elements to sink to the core, while _____ elements such as ________ and _______ , stay near the crust
Heavier
Lighter
Oxygen and silicon
First column of periodic table
Form bonds with silicon so enhanced concentration of these elements found at the crust
Radiogenic isotopes
- radioactive and decay at known rates
- unstable
- used for radiometric dating
Radiogenic coupling example
87Rb (unstable) to 87 Sr (stable)
By 1 half life the parent and daughter atoms are
50:50
Have equal concentrations
What time of bonding is found in most minerals
Ionic bonding
Structure of diamond versus structure of graphite
- both covalent bonding
- diamond has strong bonds whereas graphite (forms sheet bonds) which are weaker
- same chemical composition; only differ in their framework
Bonding in solids typically produces a __________
Crystal lattice
Definition of a crystal
Regular arrangement of atoms (crystal lattice)
This arrangement is responsible for many mineral properties
Minerals are a __________ of crystals
Subset
All minerals are crystals but not all crystals are minerals
Four criteria for a crystal to be called a mineral
- Naturally occurring
- Solid
- Specific chemical composition or range of compositions (I.e.., constant composition that can’t change into something else)
- Repeating atomic configuration-crystal structure or crystalline
A rock is
A mixture of minerals
Most common type of mineral in Earth’s crust
- silicate anion or the tetrahedron (SiO4)4-
- combination of Si4+ with 4 O2-
Minor minerals
Oxides Carbonates Sulfides Native elements Sulphates Phosphates
The silicate anions can be found as
Isolated tetrahedra
Polymerize into pairs, rings, sheets, chains, or frameworks
Isolated tetrahedra
- single tetrahedron
- olivine (Mg2SiO4)
- cleavage: none
Held together by ionic bonds
Single chain silicate
- single chain
- pyroxene group CaMg(SiO4)2 (variety: diopside)
- cleavage: two directions at 90 degrees
Double chain silicates
- double chain
- Amphibole group Ca2Mg5(Si4O11)2(OH)2 (variety: tremolite)
- cleavage: two directions at 120 degrees
Sheet silicates
- Mica
- forms a sheets
- cleavage: one direction
Framework silicates
Feldspar:
- 3D network
- cleavage: two directions at 90 degrees
Quartz:
- undisturbed pure network
- cleavage: none
What are the most abundant minerals in the continental crust
Silicates (95% of all minerals in the crust)
Mineralogy of Earth’s mantle
Upper: dominantly silicates
Lower: silicates and oxides
What are the most common types of silicates in the earth’s crust
Feldspar at 60%
Quartz at 15%
Reminding 20% are other forms of silicates (5% non silicates)