Lecture 3 Flashcards
Anionic emulsifier uses
soaps, detergents
Cationic emulsifier uses
amines, quaternary ammonium compounds
Nonionic emulsifier uses
ethoxylates, polyglyceryl esters, acylglucosides
Amphoteric emulsifier uses
betaines
A surfactant becomes more hydrophobic when it has
Longer hydrocarbon tail, more tails, or a smaller nonionic headgroup
A surfactant becomes more hydrophilic when it
is ionic, has more nonionic headgroup units, has a shorter tail
HLB
A measure of how hydrophilic a surfactant is, 1 (most hydrophobic) - 20 (most hydrophilic)
HLB of 1-3
defoamer
HLB of 3-7
W/O emulsifier
HLB of 7-9
wetting agent
HLB of 8+
O/W emulsifier
HLB of 12+
detergent, solubilizer
What kind of surfactant was HLB designed for?
Nonionic
HLB theory does not take into account…
Electrical double layer of ionics, temperature effects of nonionics, fatty alcohols, concentration of emulsifier, or phase volume.