Lecture 20 Flashcards

1
Q

what type of burn pattern suggests an accelerant was used (4)

A

severe and localised damage

not uniform across a floor

coming out from the source and expanding due to how liquids absorb through materials

a ‘sloshing’ pattern or spots just outside of the main part are likely to suggest a liquid was used

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2
Q

what is meant by a streamer or a trailer spot of accelerant

A

the little spot seen just away from the main area

suggesting liquid has splashed on a hard floor

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2
Q

what is meant by a smoke record and what is it used for

A

the smoke deposits left on all open surfaces

a good indicator of what may have happened at a scene

regions without smoke deposits are likely to have been covered

glass can show if broken before or after fire
objects on desks leave ‘shadows’
door frames show door position

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3
Q

what three things can be used to help reconstruct a fire scene

A

witness statements

pre-fire photos - use of social media and digital records make this easier

matching objects up to burn patterns

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3
Q

what three things are done/used by firefighters that can destroy a fire scene

A

high pressure hoses

windows smashed for ventilation

items cleared out to take away fuel that could increase fire

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3
Q

what do arcing wires develop

what does this suggest

A

beads at the ends

this suggests the electrical fault was prior to the fire

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4
Q

why is the excavation of the debris at a fire scene needed

A

debris may have fallen and could cover the seat of the fire or remnants of ignition sources

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5
Q

what type of electrical good may be the cause of a fire

A

counterfeit ones e.g chargers

due to design faults or incorrect use

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6
Q

what can excess current in a cable do

A

melt the insulation and this means wires can come into contact

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7
Q

fires cause ……. but ……. also cause fires

A

electrical faults

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8
Q

what are two examples of timing devices that may be used in an arson

A

a candle burning until it reaches a fuel source

soldering connections into an automated socket timer

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9
Q

what information is lab testing of samples used for

A

information regarding the ignition of a fire

in the search of liquid residues

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10
Q

what is the presence of accelerants at a scene evidence but not proof of

how are these identified

A

arson

using chemical analysis

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11
Q

where is unburnt accelerant likely to be at a scene

A

within porous materials

carpets, floorboards, upholstery, plaster, rags, floor cracks, concrete

these places are where we want to swab

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12
Q

where is unburnt accelerant less likely to be present

A

when flashover has occurred

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13
Q

what can be sprinkled over concrete surfaces to absorb traces of accelerant

A

absorbent mineral powders e.g diatomaceous earth or celite

disposable nappies have also seen to be used in an emergency

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14
Q

what three methods can be used for the detection of accelerants for on site analysis

but what does this do and what else is needed for evidence to go to court

A

portable GC-MS or in lab

sniffer dogs = less reliable but high sensitivity

portable hydrogen sniffer - organic vapours affect the electrical conductivity of a semiconductor detector

only indicates possible accelerants, lab samples and analysis is still needed

15
Q

what three samples are needed from a fire scene

A

fire sample = near as possible to the seat of the fire

comparative control sample = same material as fire sample but from elsewhere in the room and uncontaminated with accelerant

negative control sample = tools and containers of the same type used in the sampling process (ensures no contamination)

15
Q

why is time of the essence to collect unburnt accelerants

A

they are volatile liquids so need to collect before they evaporate

15
Q

is it illegal to possess accelerants such as petrol, diesel or butane

16
Q

what samples should be taken from a suspect of a fire scene if there is one

A

clothing, materials from thei premises, hand swabs

17
Q

how could samples from a fire scene be packaged (5)

A

in airtight containers so they can retain long chain hydrocarbons and aromatic molecules e.g toluene and xylene

ordinary evidence bags are too porous

bags must be free of plasticisers - seal by knotting the neck and sealing with a cable tie, often see double bagging of an inner nylon and then outer polyethylene or polypropylene

glass jars and metal lids - lid needs to withstand vapour pressure of liquids

metals cans - not lined with plastic as this is a hydrocarbon, resistant to puncture but not good for corrosive samples

18
Q

give 4 types of samples that may be taken from a fire scene

A

flooring where accelerant was
(include burnt and unburnt and underlay, at least 1m^2)

swab-able surfaces
(tiles and lightbulbs)

floorboards

soil
(under completely burnt floorboards)

ALWAYS REMEMBER CONTROLS

19
Q

what is essential for the tracking of fire scene evidence (3)

A

accurate labelling of samples - record original location in contemporaneous notes

good record keeping ensures the chain of custody - ideally electronic records

tamper evident seals on sample bags

19
what type of tools should not be used to recover evidence from a fire scene
petrol powered tools as petrol is a type of accelerant
20
what is the name of the seal used to bag fire scene evidence
swan neck seal
21
in lab analysis what are the two types of sample analysed as well as the fire scene sample
a positive control = the volatile liquid, packaged and treated the same as the scene sample negative control from within the analysis lab, to monitor accelerant traces in lab equipment
22
when is the positive control sample normally analysed in the lab
at the end of the analytical sequence to reduce the risk of contamination
23
what is the name of the two methods used for sampling possible accelerant traces collected from a scene
passive headspace sampling dynamic headspace sampling
24
what is passive headspace sampling
the vapour in a sealed container is exposed to activated charcoal which is a chemical adsorbent where it is trapped for analysis later stored at 60-80degrees for 2 hours can also use tenax
25
what is dynamic headspace sampling
vapour is drawn from the sample through an adsorbent using a flow of carrier gas e.g dry nitrogen the adsorbent is activated charcoal or tenax can be used with alcohols or ketones so applicable and low detection limit
26
how are accelerant traces removed from the adsorbent in the two sampling methods discussed how are these samples then analysed
they are eluted using a solvent such as pentane, diethyl ether or carbon disulfide then analysed by GC - sample is injected where is it vaporused - carried into a separating column by a inert carrier gas e.g helium, nitrogen - column separates solutes by adsorption and each has its own retention time - lower molecular weight tend to be eluted earlier
26
what is TENAX
a porous polymer based on diphenylene oxide which traps organic volatiles but has low affinity for water
27
what is meant by a ramping cycle when is this used
a programmed change in tend used in the GC analysis used when a sample has a broad boiling point range
28
can aromaticity affect retention time
yes
29
what does retention time primarily rely on secondarily
molecular mass the molecule structure = linear, branched, cyclic, aromatic
30
what type of distribution from GC is a characteristic pattern of distillate fuels (fuels fractions by distillation) what does this allow
a Gaussian distribution shown by petrol allows these fuels to be distinguished from mixtures of unrelated single substances (e.g pyrolysis products)
31
in GC analysis why may we not see any data for the first portion of the chromatogram and why a sample may not directly compare to a reference
samples at scene may become weathered due to aging or heating at the scene = evaporation of some components could also be incorrect storage of samples the most volatile and lower molecular weight components are likely to evaporate first here so wont be seen in the chromatogram
32
what three things do we need to be aware of when analysing GC data from scene samples that could suggest the presence of certain molecules so we don't misinterpret the data
1. other substances in fire residues 2. combustion and pyrolysis products of other materials than the fuel e.g carpets, carpet underlay, wood, clothing 3. fire retardants that may have been used at the scene e.g brominated hydrocarbons
32
what is something an arsonist may do to prevent an investigator tracing the accelerant/fuel they used back to them
use fuels available at the scene so no accelerant doesn't mean no arson
32
what does the NCFS ignitable liquids reference collection include when should this be used
common accelerants with mass spec data which is often coupled with GC this should not replace reference comparisons within the lab they should be used aswell
33
what can surfactants and fire suppressants used by firefighters be confused with how can we prevent this why is this a difficult kind of database
pyrolysis products of fuels and accelerants use a online database of GC retention times with things commonly used at fire scenes so the results can be compared GC retention times are not absolute they depend on the parameters of the GC analysis but these can also be defined on the database pattern matching is important of chromatograms and most fuels are complex mixtures not pure substances