Lecture 19 Flashcards
how is ignition of a fuel achieved
what are ways things can be heated up
the temperature of the fuel needs to be raised to its ignition temperature
a source of heat is imperative but different amounts for different fuel types
light
electricity
friction
contact with something hot
chemical reactions
nuclear fission
radiant heat from a fire can induce another fire - what is this the principle of
flashover - the transition of a fire in a room to a room on fire
the heat can be transferred to surrounding materials where they then heat up, produce pyrolysis products and combust
what are electrical sparks and arcs
the movement of a current through a gas which can lead to the ignition of a fuel
only in gases and vapours as it is very localised
spark = short
arc = maintained
for radiation to effectively heat a fuel what must happen
the fuel must be able to absorb more heat than it can dissipate
if this isn’t the case the material won’t heat up
when does an electrical current generate heat
when they meet resistance
how does a lighter ignite a flame
using friction
striking the flint in the lighter generates mechanical sparks which ignite a petroleum distillate vapour or butane gas
what is the amount of current a wire can carry proportional to
diameter, material and covering
what can heat build up in a wire due to (5)
excessive current for the wire
tightly coiled wires - can’t dissipate the heat
poor/loose connection
insulation breakdown - can char or melt
aluminium fittings in old wiring systems are not as good of a conductor than copper and create oxide films = heat barrier
where is a friction related fire unlikely to occur
and likely
in the home
train tracks
industrial machinery that is poorly lubricated
where may spontaneous combustions be seen to lead to a fire
in sawdust, coal dust, hay, straw and landfill waste
unsaturated soils that are soaked into rags and paper
these can mimic arson attacks but were actually causes due to heat build up
what is spontaneous combustion
what results in an equilibrium temperature being reached here
when can this result in a fire starting in the bulk of the material
when a substance has a naturally occurring exothermic reactions
heat is lost from the surface of the material but the temp inside still rises, accelerating the reaction but when this happens heat generated us lost more rapidly also
in a large quantity of a material the surface area is quite small so heat may not be able to be dissipated as quickly as it needs to - this can take hours to happen though
when does the likelihood of a fire hazard in a drying oil increase (2)
with the number of C=C bonds and when the structures have conjugation
what can cause any substance to spontaneously combust
if it builds up heat and can’t dissipate it quick enough to the point where it reaches it’s ignition temperature
what are two things an accidental fire needs evidence of before it can be ruled in or out and arson can be considered
evidence of the origin of the fire and any faults with the appliance that may have lead to the fire on accident
is excessive gas normally the cause of a fire
when is this an exception
no
when there is an explosion
some species oxidise in air such as ….. what can this lead to
potassium and sodium
can lead to a spontaneous combustion
what can thermostat failure result in
fires initiating in broken furnaces or driers therefore they are running above their operating/threshold temps so heat up more
open gas flames are common fire sources - name two places these may be seen
Bunsen burners
gas stoves
give three sources of got and burning fragments that can lead to the ignition of another fire
rubbish
bonfires
lanterns
hot and burning fragments are another type of ignition source, what are these called
sparks - bots of wood, paper, card that travel whilst flaming
do not confuse with the other type of sparks we looked at