Lattice enthalpy definitions Flashcards

1
Q

Define Lattice enthalpy

A

Formation of 1 mole of ionic lattice from gaseous ions under standard conditions

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2
Q

What does a more exothermic lattice enthalpy mean?

A

More exothermic = stringer ionic bonds

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3
Q

Why is not possible to measure lattice enthalpy directly

A

It is not possible to form 1 mole of ionic solid from its gaseous ions

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4
Q

Factors that impact lattice enthalpy

A

size of ions involved
charges on the ions
ionic bond strength

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5
Q

which is have a more negative lattice enthalpy

A

small ions because there is a stronger attraction

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6
Q

enthalpy of ionisation

A

endothermic. enthalpy change when one mole of gaseous ions are formed from 1 mole of gaseous ions

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7
Q

enthalpy of formation

A

exothermic. enthalpy change when one mole of a compound is formed from the elements in their standard states

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8
Q

enthalpy of atomisation

A

formation of ONE atom (often may look strange i.e Cl, not Cl2 or Cl-)

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9
Q

enthalpy of electron affinity

A

opposite of ionisation energy, only for non-metals, adding an electron to a non-metal to form a negative ion.

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