Lattice enthalpy definitions Flashcards
Define Lattice enthalpy
Formation of 1 mole of ionic lattice from gaseous ions under standard conditions
What does a more exothermic lattice enthalpy mean?
More exothermic = stringer ionic bonds
Why is not possible to measure lattice enthalpy directly
It is not possible to form 1 mole of ionic solid from its gaseous ions
Factors that impact lattice enthalpy
size of ions involved
charges on the ions
ionic bond strength
which is have a more negative lattice enthalpy
small ions because there is a stronger attraction
enthalpy of ionisation
endothermic. enthalpy change when one mole of gaseous ions are formed from 1 mole of gaseous ions
enthalpy of formation
exothermic. enthalpy change when one mole of a compound is formed from the elements in their standard states
enthalpy of atomisation
formation of ONE atom (often may look strange i.e Cl, not Cl2 or Cl-)
enthalpy of electron affinity
opposite of ionisation energy, only for non-metals, adding an electron to a non-metal to form a negative ion.