L4 Hydrocarbon isomers Flashcards
what is isomers?
compounds that have the same molecular formula but different molecular structures
what are the two types of isomers?
- structural isomers
- stereoisomers
what is structural isomers?
have the same chemical formula but their atoms are bonded in different arrangements
factors affecting boiling point?
- number of carbons: the higher the number of carbons the higher the boiling point + the number of possible structural isomers increases
- number of branches: the higher the number of branches the lower the boiling point because it decreases the intermolecular force
what is stereoisomers?
isomers in which all atoms are bounded in the same order but arranged differently in space
one type of stereoisomers is?
geometric isomers –> result from different arrangement of groups around a double bond
what are the conditions of geometrical isomerism?
- carbon-carbon double bond
- two unlike groups linked to each of the sides of doubly bonded carbon atoms
what does cis mean in stereoisomers (geometric isomers) ?
when two groups on the same side
what does trans mean in stereoisomers (geometric isomers) ?
when two groups are across from each other
who cannot form geometric isomers?
alkyne
alkane
1-alkene
both geometric isomers and stereoisomers ?
have different chemical and physical properties