L4 Hydrocarbon isomers Flashcards

1
Q

what is isomers?

A

compounds that have the same molecular formula but different molecular structures

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2
Q

what are the two types of isomers?

A
  • structural isomers
  • stereoisomers
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3
Q

what is structural isomers?

A

have the same chemical formula but their atoms are bonded in different arrangements

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4
Q

factors affecting boiling point?

A
  • number of carbons: the higher the number of carbons the higher the boiling point + the number of possible structural isomers increases
  • number of branches: the higher the number of branches the lower the boiling point because it decreases the intermolecular force
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5
Q

what is stereoisomers?

A

isomers in which all atoms are bounded in the same order but arranged differently in space

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6
Q

one type of stereoisomers is?

A

geometric isomers –> result from different arrangement of groups around a double bond

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7
Q

what are the conditions of geometrical isomerism?

A
  1. carbon-carbon double bond
  2. two unlike groups linked to each of the sides of doubly bonded carbon atoms
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8
Q

what does cis mean in stereoisomers (geometric isomers) ?

A

when two groups on the same side

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9
Q

what does trans mean in stereoisomers (geometric isomers) ?

A

when two groups are across from each other

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10
Q

who cannot form geometric isomers?

A

alkyne
alkane
1-alkene

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11
Q

both geometric isomers and stereoisomers ?

A

have different chemical and physical properties

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