L10 - Carbohydrates II Flashcards
Glycosidic Bonds
Condensation reaction between an anomeric carbon and hydroxyl group
Reducing Sugars
Sugars with free aldehyde or ketone groups
In solution, open chain forms can reduce ions e.g. Cu2+ and Cu+
Reducing end
Anomeric of one monosaccharide not linked so sugar can mutarotate
Non-reducing end
Anomeric of one end is linked so sugar cannot mutarotate
Do carbohydrates have direction?
Yes
What enzymes join sugars?
Glycosyltransferases
Where does Glycolysis take place?
Cytosol
Steps of Glycolysis
Glucose + 2 x ATP
2 x 3C molecules
2 x (Pyruvate + 2 x ATP)
Where does the Link Reaction take place?
Mitochondrial Matrix
Link reaction
Pyruvate + CoenzymeA –> Acetyl CoA
Krebs Cycle products
3 x NADH
1 x FADH2
1 x ATP (GTP)
Krebs Cycle Reactions
Acetyl CoA + Oxaloacetate –> Citrate + CoA
7 reactions return to Oxaloacetate