Kinetics Flashcards
Define activation energy
The minimum energy required before a reaction can occur. This is necessary to break the bonds within the reactants.
What must particles do in order to react?
Collide with the necessary activation energy
Be in the correct orientation
How does each factor impact a kinetics graph?
Temperature changes the slope
Concentration changes both
Volume changes the end point
What is the Maxwell-Boltzmann distribution curve?
X = energy Y = number of molecules
Most probable energy, mean/average, activation energy
Starts at (0,0) as no particles have zero energy
Area under the graph = total number of molecules
What does increasing the temperature do to the rate of a reaction?
Increases the rate
Particles move faster and many more successful collisions (increases the frequency of them)
What does increasing the concentration do to the rate of reaction?
Increases the rate
More particles in a given volume
Means increased frequency of successful collisions
What is a catalyst and what does it do?
Substance that speeds up a reaction without being used up/changed
Provides an alternative reaction pathway and lowers the activation energy
How does increasing the temperature impact the Maxwell-Boltzmann distribution curve?
Moves the curve to the right and lower
Increasing the activation energy
How does decreasing the temperature impact the Maxwell-Boltzmann distribution graph?
Shifts the curve to the left and higher
Lowers the activation energy
How does a catalyst affect the Maxwell-Boltzmann Distribution graph?
No change to the curve
Activation energy does shift left