Key Terms Flashcards
Accurate result
A result that’s really close to the true answer
Achiral molecule
A molecule that can be superimposed on its mirror image
Acid anhydride
A molecule formed from 2 identical carboxylic acid molecules, joined via an oxygen atom with the carbonyl groups on either side
Acid dissociation constant (Ka)
An equilibrium constant specific to weak acids that relates the acid concentration to the concentration of [H+] ions
Ka = [H+][A-] / [HA]
Acidic buffer
A buffer with a pH of less than 7 containing a mixture of a weak acid with one of its salts
Acyl chloride
A molecule which contains the functional group COCl
Acylation
When an acyl group (-COR) is added to a molecule
Addition polymer
A type of poly,we firmed by joining small alkenes (monomers) together
Adsorption
The attraction between a substance and the surface of the solid stationary phase in thin-layer chromatography, column chromatography and gas chromatography
Aim
The question an experiment is trying to answer
Alcohol
A substance with the general formula CnH(2n+1)OH
Aldehyde
A substance with the general formula CnH2nO which has a hydrogen and one alkyl group attached to a carbonyl carbon atom
Amide
A carboxylic acid derivative which contains the functional group CONH2
Amide link
The -CONH- group which is found between monomers in a polyamide
Amine
A molecule where one or more of the hydrogen atoms in ammonia have been replaced with an organic functional group, such as an alkyl or an aromatic group
Amino acid
A molecule with an amino group (NH2) and a carboxyl group (COOH)
Amphoteric
Having both acidic and basic properties
Anomalous result
A result that doesn’t fit in with the pattern of the other results in a set of data
Aromatic compounds
A compound that contains a benzene ring
Arrhenius equation
An equation that links the rate constant, k, to temperature and activation energy
Arrhenius plot
A graph where 1/temperature is plotted against ln k, where k is the rate constant
Autocatalysis
When a reaction is catalyses by one of its products
Base (of DNA)
One of 4 molecule: Adenine Thymine Cytosine Guanine They're attached to the sugar-phosphate backbone in DNA
Basic Buffer
A buffer with a pH of more than 7 containing a mixture of a weak base with one of its salts
Bidentate ligand
A ligand that can form 2 co-ordinate bonds in a complex ion
Biodegradable
Will break down naturally
Biodiesel
A mixture of methyl esters of fatty acids which can be used as a carbon neutral fuel
Bond dissociation enthalpy
The enthalpy change when all the bonds of the same type in 1 mole of gaseous molecules are broken down
Born-Haber cycle
An enthalpy change that allows you to calculate the lattice enthalpy change of formation for a system
Brønsted - Lowry acid
A proton donor
Brønsted - Lowry base
A proton acceptor
Buffer
A solution that resists changes in pH when small amounts of acid or alkali are added
Catalyst
A substance that increases the rate of a reaction by providing an alternative reaction pathway with a lower activation energy. The catalyst is chemically unchanged at the end of the reaction.
Catalyst poisoning
When impurities in a reaction mixture bind to a catalyst’s surface, blocking reactants from being absorbed and reducing the effectiveness of the catalyst
Catalytic Hydrogenation
A chemical reaction in which hydrogen is added to an unsaturated molecule by reacting the molecule with molecular hydrogen (H2) in the presence of a catalyst.
Categoric data
Data that can be sorted into categories
Cationic surfactant
A surfactant which is positively charged.
Casual link
The relationship between 2 variables where a change in one variable causes a change in the other
Cell potential (Ecell)
The voltage between 2 half-cells in an electrochemical cell
Chelate effect
When monodentate ligands are substituted with multidentate ligands, the number of particles and the entropy of the system increases without enthalpy changing significantly. Reactions that result in an increase in entropy are most likely to occur, so multidentate ligands form much more stable complexes than monodentate ligands
Chemical shift
Nuclei in different environments absorb energy of different frequencies. NMR spectroscopy measures these differences relative to a standard substance - the difference is called the chemical shift (δ)
Chiral carbon
A carbon atom that has 4 different groups attached to it
Chromatogram
A visual record (such as a pattern of spots or a graph) of the results of a chromatography experiment
Chromatography
An analytic technique which uses a mobile phase and a stationary phase to separate out mixtures into their constituent components
Cisplatin
A platinum-containing complex ion with a square planar shape that can be used as an anti-cancer drug
Cis-trans isomerism
A special type of E/Z isomerism where 2 of the groups attached to the carbon atoms around the C=C double bond are the same
Clock reaction
A reaction where, after a period of time, there’s a sudden increase in the concentration of a product
Colorimeter
An instrument for measuring how much light is absorbed by a sample
Column chromatography
A type of chromatography where the stationary phase is a column packed with a solid, and the mobile phase is a liquid solvent
Complex ion
A metal ion surrounded by co-ordinatley bonded ligands
Condensation polymer
A type of polymer formed through a series of condensation reactions
Condensation reaction
A chemical reaction in which 2 molecules are joined together and a small molecule is eliminated
Contact Process
An industrially used method of producing sulfuric acid
Continuous data
Data that can have any value on a scale
Continuous monitoring
A method of following a reaction by monitoring the formations of a product or the loss of a reactant, over the course of a reaction
Control variable
A variable that is kept constant in an experiment
Co-ordinate bond
A covalent bond in which both electrons in the shared pair come from the same atom (also called a dative covalent bond)
Co-ordinate number
The number of co-ordinate bonds that are formed with the central metal ion in a complex ion
Correlation
The relationship between 2 variables
Corrosive substance
A substance that may cause chemical burns
d-block
The block of elements in the middle of the periodic table
d sub-level
A type of sub-level. Each can hold 10 electrons
Data Logger
A device that can record data readings automatically at set intervals and store them to be looked at later
Dative Covalent bond
A covalent bond in which both electrons in the shared pair come from the same atom (also called a co-ordinate bond)
Dependent variable
The variable that you measure in an experiment
Deuterated solvent
A solvent which has had all of its hydrogen atoms exchanged for deuterium atoms
Deuterium
An isotope of hydrogen. It contains one neutron, one proton and one electron
Diprotic acid
An acid that releases 2 H+ ions per molecule
Discrete data
Data that can only take certain values
Distillation
A method of separating liquids with different boiling points by generally heating them
Disulfide bond
A covalent bond between sulfur atoms in 2 different thiol groups
DNA
Deoxyribonucleic acid - 2 complementary polynucleotide chains joined together in a double helix structure
Double helix
A shape formed by 2 helices twisted around each other
Drying agent
An anhydrous salt, such as magnesium sulfate or calcium chloride, that can be used to remove water from an organic product
E/Z isomerism
A type of stereoisomerism that is caused by the restricted rotation about a C=C double bond. Each of the carbon atoms must have 2 different groups attached
Electric heater
A piece of equipment used to heat a reaction mixture, consisting of a plate of metal that is heated to a set temperature
Electrochemical cell
An electrical circuit made from 2 metal electrodes dipped in salt solutions and connected by a wire
Electrochemical series
A list of electrode potentials written in order from most negative to most positive
Electrode potential
The voltage measured when a half-cell is connected to a standard hydrogen electrode
Electromotive force (EMF)
Another name for cell potential
Electrophile
An electron deficient (and usually positively charge)species which is attracted to regions of high electron density
Electrophilic substitution
A reactions mechanism where an electrophile substitutes for an atom (or group of atoms) in a molecule
Enantiomer
A molecule that has the same structural formula as another molecule but with 4 groups arranged around a chiral carbon atom so that it is a non-superimposable mirror image of the other molecule
End point
The point in a titration at which all the acid is just neutralized and the pH curve becomes vertical
Endothermic reactions
A reaction that absorbs energy (ΔH is positive)
Energy gap (ΔE)
The amount of energy needed for an electron to transfer to a higher orbital
Enthalpy change of atomistion of a compound (ΔHat)
The enthalpy change when 1 mole of a compound in its standard states is converted to gaseous atoms
Enthalpy change of atomisation of an element (ΔHat)
The enthalpy change when 1 mole of gaseous atoms is formed from an element in its standard states
Enthalpy change of formation (ΔH f)
The enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions
Enthalpy change of hydration (ΔHhyd)
The enthalpy change when 1 mole of aqueous ions is formed from gaseous ions
Enthalpy change of solution (ΔH sol)
The enthalpy change when 1 mole of an ionic substance dissolves in enough solvent to form an infinitely dilute solution
Entropy (S)
A measure of the amount of disorder in a system (e.g. the number of ways the particles can be arranged and the number of ways that the energy can be shared out between the particles)
Enzyme
A protein that acts as a biological catalyst
Equilibrium constant
Kp
A ratio worked out from the partial pressures of the gaseous products and reactants once a reversible reaction has reached equilibrium
Ester
A molecule that contains the functional group RCOOR
Ester link
The -COO- group which is found between monomers in a polyester
Esterification
Forming an ester by heating a carboxylic acid and an alcohol in the presence of a strong acid catalyst
Exothermic reaction
A reaction that gives out energy (ΔH is negative)
Fatty acid
A long chain carboxylic acid which can combine with glycerol to form a fat or an oil
Feasible reaction
A reaction that, once started, will carry on to completion, without any energy being supplied to it
Fehling’s solution
A blue solution of complexed coppe(II) ions dissolved in sodium hydroxide which can be used to distinguish between aldehydes and ketones