Kc and equilibria Flashcards
equilibrium
state of balance between opposing forces or actions
establishing equilibrium
-only reactants first
-rate of forward dec. as reactants used up
-products made as time goes by
-rate of backwards inc. as products made
-forward + backward rates are equal
-dynamic equilibrium
dynamic equilibrium
- only in closed system
- forward + backwards at equal rates
- conc. of products + reactants equal
Le chatelier’s principle
position of equilibrium will shift to oppose a change made to it
Changes in conc.
- if increased, shift to opposite direction
- if decreased, shift in that direction
changes in pressure
- if increased, shift side with less moles
- if decreased, shift side with more moles
- pressure=volume
exothermic
-energy released
-temp of surroundings increase
-enthalpy is negative
endothermic
-absorb energy
-temp of surroundings decrease
-enthalpy change is positive
changes in temperature
-if increased, shift in endothermic direction
-if decreased, shift in exothermic direction
catalyst definition
speeds up rate of reaction by providing an alternative pathway with lower activation energy
compromised conditions for the haber process
200 atm
450 degrees celsius
catalyst
Kc definition
numerical value indicating the position of equilibrium
Kc >1
more products than reactants
eq. shifts to right
Kc < 1
more reactants than products
eq. shifts to the left
Kc=1
dynamic equilbrium