Kc and equilibria Flashcards

1
Q

equilibrium

A

state of balance between opposing forces or actions

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2
Q

establishing equilibrium

A

-only reactants first
-rate of forward dec. as reactants used up
-products made as time goes by
-rate of backwards inc. as products made
-forward + backward rates are equal
-dynamic equilibrium

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3
Q

dynamic equilibrium

A
  • only in closed system
  • forward + backwards at equal rates
  • conc. of products + reactants equal
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4
Q

Le chatelier’s principle

A

position of equilibrium will shift to oppose a change made to it

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5
Q

Changes in conc.

A
  • if increased, shift to opposite direction
  • if decreased, shift in that direction
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6
Q

changes in pressure

A
  • if increased, shift side with less moles
  • if decreased, shift side with more moles
  • pressure=volume
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7
Q

exothermic

A

-energy released
-temp of surroundings increase
-enthalpy is negative

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8
Q

endothermic

A

-absorb energy
-temp of surroundings decrease
-enthalpy change is positive

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9
Q

changes in temperature

A

-if increased, shift in endothermic direction
-if decreased, shift in exothermic direction

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10
Q

catalyst definition

A

speeds up rate of reaction by providing an alternative pathway with lower activation energy

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11
Q

compromised conditions for the haber process

A

200 atm
450 degrees celsius
catalyst

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12
Q

Kc definition

A

numerical value indicating the position of equilibrium

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13
Q

Kc >1

A

more products than reactants
eq. shifts to right

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14
Q

Kc < 1

A

more reactants than products
eq. shifts to the left

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15
Q

Kc=1

A

dynamic equilbrium

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16
Q

when to use ice box

A

given initial mol and 1 equil. conc

17
Q

when to use x box

A

given initial mol and Kc value