kc Flashcards

1
Q

how is dynamic equilibrium reached

A

at the start of the reaction the forward reaction is fast and the backward reaction is slow
after the start the reverse reaction speeds up as the forward reaction slows down
the rate of the forward reaction becomes the same as the rate of forward reaction

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2
Q

dynamic meaning

A

the forward and backward reactions proceed at equal rates and happen simultaneously

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3
Q

equilibrium meaning

A

the concentration of the reactants and products are constant

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4
Q

state le chateliers principal

A

the position of equilibrium will shift to oppose a change made to the system

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5
Q

CO + H2O <-> CO2 + H2
if concentration of CO is increased…

A

the equilibrium will shift to the right to oppose the addition of CO so yeild of CO2 and H2 increases

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6
Q

2NO2 <-> N2O4
if pressure is increased

A

there are fewer moles on the right
the equilibrium shift to the right to oppose the increase in pressure
so yeild of N2O4

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7
Q

how does a decrease in volume affect pressure

A

increase in pressure

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8
Q

describe an exothermic reaction

A

realises heat energy
temperature of surroundings increases
enthaply change is negative

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9
Q

CH4 + H2O <-> CO + 3H2
-206KJmol-1

if temperature of the reaction is decreased …

A

forward reaction is exothermic
the equilibrium shifts to the right to oppose the decreases in temperature
yeild of CO +H2 increases

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10
Q

what happens when a catalyst is added reversible reaction

A

the rate of both the forwards and reverse reactions increase equally
there is no change to the position of the equilibrium
dynamic equilibrium is reached faster

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11
Q

why are compromised conditions necessary

A

higher pressures are too exspensive
45O°C gives a good yeild in a fast time

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12
Q

expression for Kc

A

Kc = [products]/[reactants]

molar ratio is the power

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13
Q

what is the meaning of Kc

A

if Kc is greater then 1 then there are more products than reactants at equilibrium and the equilibrium is shifted to the right

if Kc is less then 1then there are more reactants than products at equilibrium and the equilibrium has shifted to the left

if Kc is exactly 1 then the concentration of the products is equal to the concentration of reactants

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14
Q

what affects Kc

A

pressure doesn’t affect Kc
temp increase = equilibrium shifts endothermic direction

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