kc Flashcards
how is dynamic equilibrium reached
at the start of the reaction the forward reaction is fast and the backward reaction is slow
after the start the reverse reaction speeds up as the forward reaction slows down
the rate of the forward reaction becomes the same as the rate of forward reaction
dynamic meaning
the forward and backward reactions proceed at equal rates and happen simultaneously
equilibrium meaning
the concentration of the reactants and products are constant
state le chateliers principal
the position of equilibrium will shift to oppose a change made to the system
CO + H2O <-> CO2 + H2
if concentration of CO is increased…
the equilibrium will shift to the right to oppose the addition of CO so yeild of CO2 and H2 increases
2NO2 <-> N2O4
if pressure is increased
there are fewer moles on the right
the equilibrium shift to the right to oppose the increase in pressure
so yeild of N2O4
how does a decrease in volume affect pressure
increase in pressure
describe an exothermic reaction
realises heat energy
temperature of surroundings increases
enthaply change is negative
CH4 + H2O <-> CO + 3H2
-206KJmol-1
if temperature of the reaction is decreased …
forward reaction is exothermic
the equilibrium shifts to the right to oppose the decreases in temperature
yeild of CO +H2 increases
what happens when a catalyst is added reversible reaction
the rate of both the forwards and reverse reactions increase equally
there is no change to the position of the equilibrium
dynamic equilibrium is reached faster
why are compromised conditions necessary
higher pressures are too exspensive
45O°C gives a good yeild in a fast time
expression for Kc
Kc = [products]/[reactants]
molar ratio is the power
what is the meaning of Kc
if Kc is greater then 1 then there are more products than reactants at equilibrium and the equilibrium is shifted to the right
if Kc is less then 1then there are more reactants than products at equilibrium and the equilibrium has shifted to the left
if Kc is exactly 1 then the concentration of the products is equal to the concentration of reactants
what affects Kc
pressure doesn’t affect Kc
temp increase = equilibrium shifts endothermic direction