Ionisation Energy Flashcards
Define first ionisation energy
The energy required to remove the electrons from each atom of 1 mole of gaseous atoms of an element in order to form 1 mole of gaseous 1+ ions
The lower the ionisation energy, the ______ it is to lose electrons
Easier
Ionisation Energy Equation
X(g) —> X-(g) + e-
Successive ionisation energies from the same shell require
more energy
3 Factors affecting ionisation
Atomic radii, electron shielding and nuclear charge
TREND DOWN A GROUP
Ionisation energy decreases
TREND ACROSS A PERIOD
Generally increases; with some anomalies
Anomalies across a period (where ionisation energy decreases)
Group 2 to Group 3 and Group 5 to 6
Oxygen has a lower ionisation energy than _____
Nitrogen
Boron has a lower ionisation energy than ______
Beryllium
Why does Boron have a lower ionisation energy than Beryllium?
Boron’s outer electron is removed from the 2p sub shell, whereas Beryllium’s is from the 2s sub shell. As Boron’s outer electron is further away from the nucleus there is less nuclear attraction.
Across a period nuclear charge
Increases as the proton number increases
Across a period electron shielding
Remains the same as they have the same number of shells
Across a period atomic radius
Decreases, as electron shells are drawn closer to the nucleus due to the increasing nuclear charge.
Down a group electron shielding
Increases