Introduction to Organic Chemistry Flashcards

1
Q

Define empirical formula.

A

Simplest whole number ratio of atoms in a molecule

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2
Q

Define molecular formula

A

Gives the actual number of atoms of different elements in a molecule

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3
Q

Define displayed formula

A

Shows every atom and every bond in a molecule

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4
Q

Define structural formula

A

Shows arrangement of atoms in a molecule without showing every bond

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5
Q

Define skeletal formula

A

Drawn as lines with each vertex being a carbon atom. Carbon atoms not drawn, assumed each C atom has all unspecified bonds as C-H

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6
Q

Give the suffixes for:
a) Nodoublebonds
b) Atleastonedoublebond c) Analcohol
d) Analdehyde
e) Aketone
f) Acarboxylicacid

A

a) Nodoublebonds-ane
b) Atleastonedoublebond-ene
c) Analcohol-ol d) Analdehyde-al e) Aketone-one
f) Acarboxylicacid-oicacid

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7
Q

Give the prefixes for:
a) CH3 group b) C2H5 group c) C3H7 group d) C4H9 group e) Clgroup
f) Brgroup g) Igroup
a) CH3 group methyl- b) C2H5 group ethyl-
c) C3H7 group propyl- d) C4H9 group butyl- e) Clgroupchloro-
f) Brgroupbromo- g) Igroupiodo-

A

a) CH3 group methyl- b) C2H5 group ethyl-
c) C3H7 group propyl- d) C4H9 group butyl- e) Clgroupchloro-
f) Brgroupbromo- g) Igroupiodo-

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8
Q

Define structural isomerism

A

When molecules have the same molecular formula but different structural formula

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9
Q

What is positional isomerism?

A

Functional group is attached to the main chain at a different place

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10
Q

What is functional group isomerism?

A

Same atoms but a different functional group due to a different arrangement of atoms

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10
Q

What is chain isomerism?

A

Hydrocarbon chain organised differently e.g. branched chains

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11
Q

Define stereoisomerism.

A

When molecules have the same structural and molecular formula, but have a different arrangement of atoms in space

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12
Q

What is E-Z isomerism and how are the E and Z isomers decided?

A

E-Z isomerism is caused by the limited rotation about C=C double bonds
If the two substituents with the highest molecular mass are on the same side of the double bond, it is the Z (zusammen) isomer
If they are on different sides, it is the E (entgegen) isomer

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