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Chemistry > Acids and Bases - Physical 2 > Flashcards

Acids and Bases - Physical 2 Flashcards

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1
Q

Define a Bronsted-Lowry acid

A

Proton donor

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2
Q

Define a Bronsted-Lowry base

A

Proton acceptor

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3
Q

What ion causes a solution to be acidic? (2 answers) Name and formula

A

H+ (hydrogen ion) or, more accurately, H3O+
(oxonium ion), as protons react with H2O to form it

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4
Q

Write an equation for the ionisation of water (2)

A

2H2O (l) ⇌ H3O+ (aq) + -OH (aq)

OR

H2O(l)⇌H+ (aq)+-OH(aq)

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5
Q

What ion causes a solution to be alkaline?

A

-OH (hydroxide ion)

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6
Q

What is the value of Kw at 298K? /25 degrees celsius

A

1.0 x 10-14

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6
Q

Derive Kw using the equation for ionisation of water

A

please check - actually do

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7
Q

What physical factors affect the value of Kw? How do they affect it?

A

Temperature only - if temperature is increased, the equilibrium moves to the right so Kw increases and the pH of pure water decreases

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8
Q

Why is pure water still neutral, even if pH does not equal 7?

A

[H+] = [-OH]

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9
Q

Give an expression for pH in terms of H+

A

pH = -log10[H+]

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10
Q

What is the relationship between pH and concentration of H+?

A

Lower pH = higher concentration of H+

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11
Q

If two solutions have a pH difference of 1, what is the difference in [H+]?

A

A factor of 10

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12
Q

How do you find [H+] from pH?

A

[H+] = 10-pH

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13
Q

How do you find [OH-] from pH? (at 298K)

A

Find [H+], use Kw(equal to 1 x 10-14 at 298K) to calculate [-OH]

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14
Q

What is different when finding [H+] from the concentration of diprotic and triprotic acids?

A

Need to multiply the concentration of the acid by the number of protons to find [H+]

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15
Q

How do you calculate the pH of a strong alkaline solution?

A

Use Kw to calculate [H+] from [OH-] Use pH=-log[H+]

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16
Q

Define the term strong base.

A

One which fully dissociates in water (XOH → X+ + -OH)

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17
Q

Define the term strong acid

A

One which fully dissociates in water ( HX → H+ + X-)

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18
Q

Give some examples of strong acids

A

HCl, H2SO4, H3PO4

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19
Q

What is the difference between concentrated and strong?

A

Concentrated means many mol per dm3, strong refers to amount of dissociation

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20
Q

What is a weak acid and a weak base?

A

Weak acids and bases do not fully dissociate in water. They only partially dissociate into their ions.

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21
Q

Give some examples of strong bases

A

NaOH, CaCO3, Na2CO3

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22
Q

How would you work out the pH of a weak acid?

A

Use the equation for Ka, subbing in values for [A-] and [HA].
Use pH=-log[H+] equation to find pH

23
Q

Give some examples of weak acids

A

CH3COOH (ethanoic), any organic acid

24
Q

What is Ka? (expression)

A

check seriously

24
Q

Give some examples of weak bases

A

NH3

24
Q

What is a titration?

A

The addition of an acid/base of know titration to a base/acid of unknown titration to determine the concentration. An indicator is used to show that neutralization has occurred, as is a pH meter.

25
Q

Draw the titration curve for a weak acid with a weak base added

A

check

25
Q

Draw a diagram of the equipment that could be used for a titration.

A

check

25
Q

Draw the titration curve for a strong acid with a weak base added

A

check

26
Q

Draw the titration curve for a strong acid with a strong base added

A

check

27
Q

Draw the titration curve for a weak acid with a weak base added

A

check

28
Q

Draw the titration curve for a weak acid with a strong base added

A

check

29
Q

Define the term equivalence point.

A

The point at which the exact volume of base has been added to just neutralise the acid, or vice-versa.

30
Q

What generally happens to the pH of the solution around the equivalence point?

A

There is a large and rapid change in pH, except in the weak-weak titration.

31
Q

What indicator would you use for a strong acid-strong base titration?

A

Phenolphthalein or methyl orange, but phenolphthalein is usually used as clearer colour change.

32
Q

What is the end point?

A

The volume of acid or alkali added when the indicator just changes colour. If the right indicator is chosen, equivalence point = end point.

33
Q

How would you calculate the concentration of a reactant if you know the volume and conc of the other reactant and the volume of that reactant
added

A

Calculate mols of one reactant

use balanced equation to work out mols of the other

Use conc = mol/vol to calculate concentration

34
Q

What are the properties of a good indicator for a reaction? (3)

A

Sharp colour change (not gradual) - no more than one drop of acid/alkali needed for colour change
End point must be the same as the equivalence point, or titration gives wrong answer.
Distinct colour change so it is obvious when the end point has been reached.

35
Q

What indicator would you use for a strong acid-weak base titration?

A

Methyl orange

36
Q

What indicator would you use for a strong base-weak acid titration?

A

Phenolphthalein

36
Q

What indicator would you use from a weak acid-weak base titration?

A

Neither methyl orange or phenolphthalein is suitable, as neither give a sharp change at the end point.

37
Q

What colour is methyl orange in acid? In alkali? At what pH does it change?

A

Red in acid; yellow in alkali. Changes at about pH = 4-5. Approx same as pKa value

38
Q

What colour is phenolphthalein in acid? In alkali? At what pH does it
change?

A

Colourless in acid; red in alkali. Changes at about pH = 9-10. Approx same as pKa value

39
Q

What is the half-neutralisation point?

A

When volume = half the volume that has been added at the equivalence point

40
Q

Define a buffer solution

A

A solution that resist changes in pH when small amount of acid/alkali are added.

41
Q

Write a reaction for an acidic buffer with added acid

A

A- + H+ → HA, opposes addition of H+

41
Q

What do acidic buffer solutions contain in general terms?

A

A weak acid and a soluble salt of that acid that fully dissociates.

42
Q

Write a reaction for an acidic buffer with added alkali.

A

HA+OH- →H2O+A-

43
Q

How else can you achieve an acidic buffer solution other than just mixing the
constituents?

A

Neutralise half of a weak acid (meaning the acid must be in excess) with an alkali - this forms a weak acid / soluble salt mixture.

44
Q

What do basic buffer solutions contain in general terms?

A

Weak base and soluble salt of that weak base

45
Q

How can you calculate the pH of buffer solutions?

A

Use the Ka of the weak acid, sub in [A- and [HA], calculate [H+] → pH

46
Q

How can you calculate the new pH of a buffer solution when acid or base is added?

A

Calculate number of moles of H+ and A- and HA before acid or base is added. Use equations to work out new moles of A- and HA → find [H+] → pH

47
Q

Which buffer system maintains blood pH at 7.4? What happens when acid/alkali is added?

A

H+ + HCO3– ⇌ CO2 + H2O
Add OH- → reacts with H+ to form H2O, then shifts equilibrium left to restore H+ lost
Add H+ → equilibrium shifts to the right, removing excess H+

48
Q

What products are buffers found in?

A

Shampoos, detergents → important to keep pH right to avoid damage to skin, hair, fabrics

Chemistry (20 decks)

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