intro to organic chem Flashcards

1
Q

what is general formula

A

algebraic formula that can be applied to chemicals in the ‘family’

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2
Q

general formula of alkanes

A

Cn H2n+2

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3
Q

general formula of alkenes

A

Cn H2n

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4
Q

general formula of alcohols

A

Cn H2n+1

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5
Q

what is molecular formula

A

the actual number of atoms in a molecule or element

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6
Q

what is structural formula

A

the arrangement of atoms in a molecule without showing all the bonds

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7
Q

what is skeletal formula

A

show the bonds of the carbon skeleton only. hydrogen and carbon atoms not shown but functional groups are

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8
Q

what is displayed formula

A

shows the arrangement of atoms showing all the bonds and atoms in the molecule

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9
Q

what is the homologous series

A

the homologous series of a group of compounds have the same functional group and general formula

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10
Q

successive members of the same homologous series increases by …

A

CH2

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11
Q

stem names for number of carbons

A

1- meth
2- eth
3- prop
4- but
5- pent
6- hex

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12
Q

what is the prefix/suffix of alkanes

A

-ane

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13
Q

what is the prefix/suffix of alkenes

A

-ene

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14
Q

what is the prefix/suffix of alcohols

A

-ol

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15
Q

what is the prefix/suffix of aldehydes

A

-al

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16
Q

what is the prefix/suffix of ketones

17
Q

what is the prefix/suffix of carboxylic acids

18
Q

what is the prefix/suffix of halogenoalkanes

A

fluoro- bromo- etc

19
Q

what is the functional group of alkanes

20
Q

what is the functional group of alkenes

21
Q

what is the functional group of alkyne

22
Q

what is the functional group of alcohol

23
Q

what is the functional group of halogenoalkane

24
Q

what is the functional group of carboxylic acid

25
what is the functional group of aldehyde
RCHO
26
what is the functional group of ketone
RCOR
27
what is the functional group of amine
R-NH2
28
what is the functional group of nitrile
R-CN
29
what is a mechanism
a chemical mechanism shows the movement of electrons during a chemical reaction
30
what are structural isomers
have the same molecular formula but a different structural formula
31
what are chain isomers
same molecular formula but different arrangement of the carbon skeleton
32
what are positional isomers
same molecule formula but different position of the functional group on the carbon skeleton
33
what are functional group isomers
same molecular formula but different functional group
34
what are stereo isomers and give an example
have same structural formula but a different arrangement of atoms in space an example is e/z isomerism
35
how does e z isomerism occur
the c=c bond and the atoms bonded directly to this are flat and the atoms cannot rotate around the bond and are rigid. this means u get e z isomerism
36
e isomer in ez isomerism
same groups opposite the double bond
37
z isomerism in ez isomerism
same groups on the sea side of the double bond
38
what are the cip rules
calculate atomic number of the two elements directly bonded to one C. highest priority goes to higher number. do same on other C. then determine e or z based on high priority elements