group 2 Flashcards
trend of atomic radius as we go down group 2
atomic radius increases as extra shells added
ionisation energy trend in group 2
1st ionisation energy decreases as we go down group 2- there is more shielding hence weaker attraction between the nucleus and outer electrons, the outer electrons are also further from the nucleus, although increase in protons but shielding effect overrides
melting point energy trend in group 2
metallic structures so the size of the metal ion increase but number of delocalised electrons and charge remains same means the distance between positive nuclei and electrons is bigger weakens attractive force
what is the exception of mpt trend
magnesium due to structural difference
group 2 elements react with water to form …
bases, metal hydroxides
reactivity … with water because?
increases
larger atoms and so electron further from nucleus so easier to remove and more reactive
what are exceptions to reactions with water
Be no reaction w water
Mg reacts with steam to make MgO and reacts slowly w cold water to form MgOH
solubility trend in group 2
group 2 sulfates (-2charge) become less soluble down the group
group 2 hydroxides (-1charge) become more soluble down the group
tests for sulfates
using barium chloride
-add HCl to remove carbonates
-add barium chloride
-white ppt will form if present as BaSO4 is insoluble
group 2 compounds can be used to … acids. what are some examples
neutralise
acidic soils- CaOH used to neutralise acidic soils
antacids- MgOH used to neutralise excess stomach acid
ionic equation for neutralisation
H+ + OH- => H2O
what are barium meals
barium sulfate also known as barium meal
purpose of barium meal
used to help identify problems with the digestive tract. patient drinks suspension of baso4 coating the lining of soft tissues, patient stands in an x ray machine and x rays are absorbed by barium sulphate and will show up on x ray that wouldn’t normally
why can humans ingest barium sulfate
barium compounds are toxic however because various sulfate is insoluble it can’t be absorbed into the blood
what is used to extract titanium from its ore
magnesium