energetics Flashcards

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1
Q

what is enthalpy

A

the change in energy that normally occurs during a reaction

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1
Q

what is enthalpy change

A

the heat change in a reaction at constant pressure

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2
Q

what are the standard conditions

A

100 kPa pressure
298K (25°C)

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3
Q

what are endothermic reactions

A

reactions that absorb energy from the surroundings

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4
Q

what are exothermic reactions

A

reactions that release energy to the surroundings

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5
Q

in endothermic reactions, the products are … in energy than reactants, the delta H value is …

A

higher
positive

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6
Q

in exothermic reactions, the products are … in energy than reactants, the delta H value is …

A

lower
negative

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7
Q

to break a bond, energy needs to be …

A

absorbed

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8
Q

when bonds are formed, energy is …

A

released

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9
Q

when more energy is used to break bonds than make bonds, this is an … process and so delta H is …

A

endothermic
positive

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10
Q

when more energy is used to make bonds than break bonds, this is an … process and so delta H is …

A

exothermic
negative

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11
Q

enthalpy change =

A

total energy to break bonds - total energy released forming bonds

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12
Q

what is calorimetry used to work out

A

the enthalpy change of combustion

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13
Q

why are there wind shields and a lid in a calorimetry experiment

A

a lid is planed on top to prevent heat loss and wind shields placed by the flame to prevent a draught moving the flame

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14
Q

how to calculate energy transferred from calorimetry experiment

A

q = mcΔT
q - heat energy lost or gained (J)
m - mass of all liquids (g)
c - specific heat capacity of water (4.18)
T - temperature change (K)

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15
Q

why is a polystyrene cup used for experiments

A

prevents heat loss

16
Q

how is enthalpy calculated from energy transferred

A

enthalpy = q/moles

17
Q

what is hess’s law

A

the total enthalpy change of a reaction is independent of the route taken