Intro To Organic Flashcards

1
Q

what is empirical formula

A

formula that gives the simplest whole ratio of atoms of each element in a compound

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2
Q

what is molecular formula

A

formula that gives the actual number of atoms of each element in one molecule

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3
Q

what in general formula

A

number of atoms of each element in a substance which has n carbon atoms
in a homologous series this would be the same

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4
Q

what is structural formula

A

shows how the atoms are joined together brackets used to show side chain

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5
Q

what is displayed formula

A

shows all the bonds and atoms in a molecule

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6
Q

what is skeletal formula

A

uses lines to represent bonds
each point represents a carbon atom
h atoms are not shown

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7
Q

what are the characteristics of homologous series

A
  • same general formula
  • similar chemical properties
  • similar trend in boiling points
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8
Q

what are the 3 stages in free radical substitution

A

initiation
propagation
termination

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9
Q

show the initiation of CFCl3

A

CFCl3 -> Cl* + CFCl2

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10
Q

show the two propagation stages of CFCs

A

Cl* + O3 -> ClO* + O2
ClO* + O3 -> Cl* +2O2

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11
Q

show the termination stage of CFCs

A

ClO* + ClO* -> Cl2O2

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12
Q

what is a bond making arrow

A

lone pair of electrons -> positive ion

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13
Q

what is a bond breaking arrow

A

line -> atom
happens when an atom is about to have or does have too many bonds so one breaks

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14
Q

what is a bond transfer arrow

A

line -> atom or another bond outside current bond

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15
Q

what is a stereoisomer

A

molecules with same structural formula but bonded together in different orders

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16
Q

what are the types of structural isomers

A

Chain isomerism
Positional isomerism
Functional group isomerism

17
Q

what is a structural isomer

A

same molecular formula but different structural formulae

18
Q

what is Chain isomerism

A

same molecular formula but the hydrocarbon chain is arranged differently

19
Q

what is positional isomerism

A

same molecular formula but functional group is attached to the chain at different points

20
Q

what is functional group isomerism

A

same molecular formula but different functional group

21
Q

what are the types of stereoisomers

A

geometric isomers
optical isomers

22
Q

what is geometric isomers

A

same structural formula but different arrangement around a non rotational double bond

23
Q

what is optical isomerism

A

same structural formula but different arrangement around a chiral carbon or have a non-superimposable mirror image

24
Q

what are the cip priority rules

A

1 - split double bond down the middle
2 - look at left side and apply priority to group with highest atomic number
3 - look at right and repeat
4 - compare is its the same its z and if its opposite its e