Intermolecular forces/ electronegativity Flashcards

1
Q

Name the 3 different types of forces

A

Permanent dipole to dipole interactions, Induced dipole to dipole interactions (London forces), Hydrogen bonds

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2
Q

What effects permanent dipole to dipole interactions.

A

Bigger difference in electronegativity the stronger the forces. More energy is required to overcome the forces causing a higher boiling/melting point.

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3
Q

How do London forces form

A

At any instant, an electron could be unequally distributed. This causes a partial charge to develop. An instantaneous dipole on one atom induce a dipole on a neighboring atom. (Electrostatic forces of attraction between charges).

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4
Q

In which molecules are London forces present

A

All of them.

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5
Q

What effects London forces

A

The more electrons in an atom the stronger the forces. More energy is required to overcome forces causing a high boiling/melting point.

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6
Q

When do hydrogen bonds occur

A

When hydrogen is bonded to Nitrogen, Fluorine and Oxygen. Attraction between lone pairs.

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7
Q

What angle are the hydrogen bonds

A

180 degrees

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8
Q

Order the forces in terms of their strength from weakest to strongest.

A

Induced dipole to dipole, permanent dipole to dipole, hydrogen bonds, covalent bonds, ionic bonds.

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9
Q

what features do simple molecular substances have.

A

simple molecular lattice, strong covalent bonds and they have weak forces so have a low melting point.

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10
Q

What is the solubility of simple molecular substances

A

non-polar simple substances will dissolve. Polar substances are hard to predict. It depends on if the substance is able to form hydrogen bonds with the water.

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11
Q

What causes a liquid to be miscible

A

If the liquids have similar properties so the forces can dissolve in each other.

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12
Q

What is the electrical conductivity of simple molecular substances

A

do not conduct

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13
Q

What can polar substances do

A

Be attracted to a charged rod as the rod is negative and they substance has a slight positive charge.

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14
Q

What happens when ice melts

A

When ice melts the structure collapses and molecules move closer and as they gain more energy they move further apart.

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15
Q

What structure does water have

A

Giant lattice structure.

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16
Q

Define electronegativity

A

Ability of an atom to attract the bonding electrons in a covalent bond.

17
Q

What happens the greater the electronegativity

A

It attracts more electrons and it creates a bigger permanent dipole.

18
Q

What happens when the electronegativity s the same in both atoms.

A

the electrons are shared equally

19
Q

To be a covalent bond what does the electronegativity difference value need to be

A

0

20
Q

To be an ionic bond what does the electronegativity difference value need to be

A

1.8+

21
Q

To be a polar covalent bond what does the electronegativity difference value need to be

A

0-1.8

22
Q

What determines overall dipole

A

symmetry

23
Q

What are the key phrases to use when doing electronegativity questions

A

if the molecule is symmetrical and the difference in electronegativity between different atoms.

24
Q

define covalent bond

A

strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms