INTERMOLECULAR FORCES Flashcards
what are the 3 types of intermolecular forces
dipole-dipole forces
VDW forces
hydrogen bonding
describe dipole dipole forces
when there is a dipole moment
- one side delta positive and the other delta negative
intermolecular : weak - delta plus on one molecule attracts to delta minus on another molecule
intramolecular: strong - covalent bonds join atoms within the molecule
describe VDW forces
electrons in charge clouds are constantly moving
if electrons are more at one end of the molecule there is a temporary dipole
this induces a dipole in the next molecule
temporary delta positive attracts induced delta negative in the next molecule
what affects VDW forces
- more electrons = stronger VDW forces
- bigger surface area = stronger VDW forces
describe hydrogen bonding
oxygen is very electronegative
forms a dipole (o- / h+)
lone pair on o attractred to +h
the o-h-o section is linear
when do hydrogen bonds occur
only form when f, o, n are attached to h
are represented by ———-
are longer than covalent bonds
put the intermolecular forces in order of strength
weakest
VDW
dipole dipole
hydrogen bonds
strongest