EQUILIBRIA Flashcards
are many reactions reversible or irreversible
reversible
what happens in a sealed container
all products and reactants will exist
they are in equilibrium
what does it mean if a reaction is in equilibrium
At equilibrium the concentrations of reactants / products remain constant
all products and reactants are present at equilibrium
what does it mean if equilibrium is dynamic
rate of forward reaction = rate of backwards reaction
what does shifting equilibrium to the right mean
more products
what is Le Chateliers principle
“If a constraint is imposed on a system at equilibrium, then the system will respond in such a way as to counteract the effect of that constraint”
an equilibrium will shift to oppose any change
concentration on shifting equilibrium
adding more of a reactant - shift to the right to oppose the increase in H2
adding more product - shifts to the left to oppose the increase in product
remove product - shifts to the right to oppose decrease in product
pressure (gases only) on shifting equilibrium
increase pressure - shifts to side with fewer moles to oppose the decrease in pressure
decrease pressure -shifts to the side with more moles to oppose the decrease in pressure
effect of temperature when shifting equilibrium
increase temp - shifts to endothermic side (left) to oppose increase in temperature
decrease temp - shifts to exothermic side (right) to oppose decrease in temperature
do catalysts affect equilibrium
no as catalysts increase the rate of both the forwards and backwards reaction by the same amount