EQUILIBRIA Flashcards

1
Q

are many reactions reversible or irreversible

A

reversible

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2
Q

what happens in a sealed container

A

all products and reactants will exist
they are in equilibrium

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3
Q

what does it mean if a reaction is in equilibrium

A

At equilibrium the concentrations of reactants / products remain constant
all products and reactants are present at equilibrium

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4
Q

what does it mean if equilibrium is dynamic

A

rate of forward reaction = rate of backwards reaction

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5
Q

what does shifting equilibrium to the right mean

A

more products

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6
Q

what is Le Chateliers principle

A

“If a constraint is imposed on a system at equilibrium, then the system will respond in such a way as to counteract the effect of that constraint”
an equilibrium will shift to oppose any change

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7
Q

concentration on shifting equilibrium

A

adding more of a reactant - shift to the right to oppose the increase in H2
adding more product - shifts to the left to oppose the increase in product
remove product - shifts to the right to oppose decrease in product

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8
Q

pressure (gases only) on shifting equilibrium

A

increase pressure - shifts to side with fewer moles to oppose the decrease in pressure
decrease pressure -shifts to the side with more moles to oppose the decrease in pressure

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9
Q

effect of temperature when shifting equilibrium

A

increase temp - shifts to endothermic side (left) to oppose increase in temperature
decrease temp - shifts to exothermic side (right) to oppose decrease in temperature

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10
Q

do catalysts affect equilibrium

A

no as catalysts increase the rate of both the forwards and backwards reaction by the same amount

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