ADDITION POLYMERISATION Flashcards
polymers
long chain molecules formed when lots of monomers join together
alkenes can react with other alkene molecules via addition polymerisation to form polymers
what does n represent
large number of molecules
what is the structure inside the brackets called
repeating unit
percentage atom economy of addition polymerisation
100%
reactivity of addition polymers
unreactive as strong bonds are formed and there are non-polar bonds
double bond is broken resulting in an unreactive alkane
how to draw polymers
- draw the normal alkene with the C=C bond in the middle
- add n next to the monomer
- draw the same alkene but without the double bond
- add square brackets
naming polymers
poly(X)
where X is the name of the monomer
properties of polymers with no branching
can pack closer together
stronger intermolecular forces between molecules
a strong rigid material is formed such as poly(ethene)
properties of polymers with large branches
cannot pack close together
weaker intermolecular forces between molecules
flexible material is formed such as poly(styrene)
modifying properties of polymers
plasticisers are used to modify the properties of polymers
the plasticiser molecules get between the polymer chains and push them apart
this reduces the strength of the intermolecular forces therefore more flexible
the more plasticiser added the more flexible