Intermolecular Forces Flashcards

1
Q

IMF

A
  • forces between molecules weak
  • london forces
  • permanent dipole - permanent dipole
  • hydrogen bonding
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2
Q

london forces

A
  • cause all atoms and molecules to be attracted to each other
  • electrons in charge clouds always moving really quickly
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3
Q

Dipole

A
  • any particular moment electrons in atoms are more likely to be more to one side then the other
  • this moment atom would have a temporary dipole
  • dipole can induce another temporary dipole on the opposite direction on a neighbouring atom
  • 2 dipoles are attracted to each other
  • second dipole cna induce yet another dipole in a third atom so its like a domino effect
  • electrons are constantly moving so dipoles being created and destroyed all the time
  • even tho they keep changing overall effect is for atoms to be attracted to each other
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4
Q

london forces lattice

A
  • molecules held together in a molecular lattice arrangement by weak london forces
  • simple molecular structure
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5
Q

stronger london forces

A
  • high m+bp
  • larger molecules have larger electron clouds so stronger london forces
  • more molecular surface contact and more electrons to interact
  • longer so harder to seperate
  • more energy needed to overcome london forces
  • branched chain alkanes can’t pack closely together and their molecular surfacer contact is small compared to straight chain alkanes of similar molecular mass
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6
Q

polar molecules

A
  • have permanent dipole - permanent dipole bonds
  • delta + and delta - charges on polar molecules cause weak electrostatic forces of attraction between molecules
  • pdpd bonds as well as lf
  • generally hmp+BP
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