Interfacial Phenomenon Flashcards
What is interfacial phenomenon?
the behavior of molecules at the boundaries of phases (interface)
Are intermolecular forces attractive or repulsive?
BOTH
How many interphases are there and what are they?
There are 6: S-S S-L S-G L-L L-G G-G
What is the boundary between the interphase called?
interfacial tension
When a phase in the interphase is gas, what can interfacial tension be called?
surface tension
What does surfactants do?
lower interfacial tension between ingredients; lower contact angles
γ
surface tension
What is temperature’s effect on surface tension?
surface tension decreases with increasing temperature; you must report a temperature value when giving surface tension value
What is a tensiometer?
a device used to measure interfacial tension
What are the different methods used to measure interfacial tension?
- Du Nouy Ring method
- Capillary Rise method
- Wilhemy plate method
Du Nouy Ring method equation
γ = k x F
Capillary Rise method equation
γ = (h r d g) / (2 cos θ)
Wilhemy plate method equation
F = 2(L + T)γ cos θ γ = F / (2 x F)