Inorganic Chemistry - Reactivity Series Flashcards
how are metals arranged in the reactivity series?
theyre arranged with the most reactive metals at the top, based on their reactions with water and dilute sulfuric acid or on their displacement reactions between metal oxides and aqueous solutions of metal salts
what happens when a metal reacts with another metal oxide?
a metal will displace another metal from its oxide that is lower in the reactivity series
what happens when a metal reacts with an aqueous solution of a metal salt?
a metal will also displace another metal from its salt that is lower in the reactivity series
what is the order of reactivity?
- potassium
- sodium
- lithium
- calcium
- magnesium
- aluminium
- zinc
- iron
- copper
- silver
- gold
what conditions will iron rust in?
iron rusts when oxygen and water are present
how can you prevent iron rusting?
barrier methods, galvanising and sacrificial protection
what is the barrier method?
rusting may be prevented by stopping the water and oxygen getting to the iron with a barrier of grease, oil, paint or plastic
what is galvanising?
coating in zinc prevents water and oxygen from getting to the iron, and even if the barrier is broken the more reactive zinc corrodes before the less reactive iron. during the process, the zinc loses electrons to form zinc ions
what is sacrificial protection?
zinc blocks are attached to iron to act as sacrificial anodes. zinc is more reactive than iron, so oxygen in the air reacts with the zinc to form a layer of zinc oxide instead of iron.
what is oxidation?
- the loss of electrons
- the gain of oxygen
what is reduction?
- the gain of electrons
- the loss of oxygen
what is redox?
a reaction involving oxidation and reduction
what is an oxidising agent?
a substance that gives oxygen or removes electrons (it is itself reduced)
what is a reducing agent?
a substance that takes oxygen or gives electrons (it is itself oxidised)
what happens in a reaction between dilute hydrochloric/sulfuric acid and metals?
metals which are above hydrogen in the reactivity series will react with dilute hydrochloric or sulfuric acid to produce a salt and hydrogen:
metal + acid -> salt + hydrogen
this is a displacement reaction and is exothermic