Inorganic Chemistry Flashcards
Who developed the atomic Theory
John Dalton
What is the charge of the electron?
-1.6x10^19 C (Robert Millikan)
Established the particle character of cathode rays
George Johnstone Stoney
Established the raisin bread model as a theory of atomic structure
J.J. Thompson
Who discovered that electricity can decompose compounds?
Michael Faraday
Performed an experiment on cathode rays and detected the presence of ions
Eugen Goldstein
Introduced the nuclear model of the atom, used a gold sheet; positive charge in a small region called nucleus
Ernest Rutherford
Discovered the neutron
James Chadwick
What is the charge of a proton?
1.602x10^19 C
Significant observation in chemical periodicity; named groups in triads
Johan Wolfgang Dobreiner
suggested the law of octaves
John Newlands
Published an independent version of the periodic system; organized in increasing atomic weights
Dmitri Ivanovich Mendeleev
Established the modern periodic table
Henry Mosely
Groups that belong to s/p blocks
Group 1A-8A
Alkali metals (except hydrogen)
Alkali earth metals
Aluminum
Carbon
Nitrogen
Oxygen
Halogens
Noble or Inert gasses
The transition elements belong to the ___-block
d-block
Inner transition elements belong to the f-block which consists of ______ and ______
lanthanide (4f)
actinide (5f)
Periodic Trends that: (2)
L-R : Decrease
T-B : Increase
Atomic Radius
Metallicty
Periodic Trends that: (3)
L-R : Increase
T-B : Decrease
Electronegativity
Ionization Energy
Electron Affinity
Qualities that describe the outside appearance of matter
Extrinsic properties
depend on the kind of material itself
Intrinsic Properties
Depend on the amount of matter present
Extensive Properties
Do not depend on the amount of substance present
Intensive properties
structure that is not orderly, melting point is not determined
amorphous solids
Viscosity Trends = higher or lower?
Temp
Pressure
IMF
higher temp = lower viscosity
higher pressure = higher v
stronger IMF = higher V
Vapor pressure trends = higher or lower?
Temp
Pressure
IMF
higher temp = higher vapor pressure
higher IMF = lower VP
higher VP = lower boiling point
Vapor pressure of a liquid is equal to the external pressure on its surface
Boiling point
when electrons are shared there is a _____ bond between the compounds
Covalent
an _____ bond is formed when non-metals and metals bond together because of a difference in electronegativity
ionic bond
A physical combination of two or more distinct chemical substances
Mixture
A phenomenon wherein a characteristic of suspensions and colloids is their ability to scatter light when passing through a mixture
Tyndall effect
Suspensions have a particle size larger than ______
200nm
Colloids particle size are between ________
1-200nm
The mixture or solution is heated into a vapor and condensed
Distillation
reduction ____ electrons & hydrogen
oxidation ______ electrons & hydrogen
reduction = gains
oxidation = release
acids: hydrogen ion donor
bases: hydroxide (-OH) donor
Arrhenius theory
acids: proton donor
bases: proton acceptor
Bronsted-Lowry theory
acids: electron pair acceptor
bases: electron pair donor
Lewis theory
SI unit of energy
Joule
1 joule = ___ kg m^2/s^2
1
1 cal = ____ J
1 cal = 4.184J
KeQ = equilibrium constant formula
Keq = (products)^x / (reactants)^y
states that “when a system is in equilibrium, the equilibrium shifts so as to undo, in part, the effect of disturbance”
Le Chatelier’s principle
atoms containing radionuclides
radioisotope
particles are helium atoms
alpha emission
particles are electrons (0-e)
increase in atomic number
beta emission
no change in atomic number or mass since rays are uncharged
gamma emission
(01e) decrease in atomic number
positron emission
inner shell electron is captured by the nucleus
decrease in atomic number
electron capture
splitting of heavy nuclei
nuclear fission
union of light nuclei
nuclear fusion
solutions are ____ mixtures
homogenous
two types of heterogenous mixtures are
colloids
suspensions
elements that have the same number of neutrons but have different number of protons
isotones
elements that have the same atomic number but different atomic mass number
isotopes
percent composition formula
percent composition = (molar mass of element / total molar mass of a compound) x100
MC molecular geometry on NMAT
Linear:
Tetrahedral:
Bent:
Linear: CO2
Tetrahedral: CH4 (methane)
Bent:H2O, SO4
BF3 geometry
trigonal planar
Compounds with tetrahedral arrangement (3)
CH4 (methane)
NH3 (ammonia)
H20 (bent)
Compounds with trigonal bypyramidal geometry (4)
PCl5 (phosphorus pentachloride)
SF4 (sulfur tetrafluoride)
ClF3 (Chlorine trifluoride)
I3- (triiodide)
Compounds with octahedral arrangement (3)
SF6 (Sulfur hexafluoride)
BrF5 (bromine pentafluoride)
XeF4 (xenon tetrafluoride)
orbital size and energy level
principal quantum number (n)
orbital shape
angular momentum (l)
orbital orientation
magnetic quantum number (ml)
electron spin direction
spin (ms)
Electrons will fill the lowest energy level first
Aufbau principle
no two electrons within an atomy should have an identical set of all four quantum numbers
Pauli Exclusion principle
electrons will occupy all empty orbitals in a subshell with single electrons having parallel spins before entering half-filled orbitals
Hund’s Rule
angular momentum
s
p
d
f
angular momentum
s = 0
p = 1
d = 2
f = 3
maximum electron number
s
p
d
f
maximum electron number (half will be the shell or orbital number)
s = 2
p = 6
d = 10
f = 14
ml (orientation)
s
p
d
f
ml (orientation)
s = 0
p = -1, 0, 1
d = -2, -1, 0, 1, 2
f = -3, -2, -1, 0, 1, 2, 3
the s orbital has a _____ shape
the p orbital has a ______ shape
s = sphere
p = dumbell
the valence electron can be determined according to the ______ of the element
group number
the more electronegative element gains an electron
reduction
the less electronegative element loses an electron
oxidation
bond between non-metal and non-metal
covalent bond
bond between non-metal and metal
an electron is taken by the more electronegative participant
ionic bonds
______ bonds are formed by fluorine, oxygen or nitrogen
hydrogen bonds
_____ bonds form a sea of electrons
metallic bonds
Electrons not equally shared
One part of molecule is more negative or positive
Polar molecules
Electrons equally shared
No one part of molecule is more negative or positive
Non-polar molecules
Polar Molecules ____
Non-Polar molecules ____
A. hydrophobic
B. hydrophilic
Polar Molecules: HYDROPHILIC
Non-Polar molecules HYDROPHOBIC
metal cations to delocalized electrons
metallic bonds
cations to anions
ionic bond
partially charged cation to partially charged anion
polar covalent bonds
nuclei to shared electrons
non polar covalent bonds
partially oppositely charged ions
dipole-dipole attraction
weakest intermolecular forces of attraction
london dispersion attraction
greater molecular weight = _______ london dispersion forces
higher
higher boiling point = _______ vapor pressure
higher boiling point = lower vapor pressure
higher boiling point =
higher: (3)
lower: (2)
higher boiling point =
higher: (3) IMF, MW, surface area
lower: (2) branching, VP
2 or more simpler substances (elements) combine to give a compound
Synthesis
Compound is broken down into simpler substances (elements)
Decomposition
Atom or group of atoms is replaced by another atom or group
A + BC = AC + B or AB + C
Single Replacement
Solid compound is formed
2 soluble compounds are mixed
AB+ CD = AD + BC
Double Replacement
Reaction between hydrocarbon and oxygen to produce carbon dioxide, water and heat.
An exothermic reaction
Combustion
An acid reacts with a base to produce salt and water
HA + BOH –> H2O + BA
Neutralization
Electron transfer occurs
Reduction-Oxidation
an oxidizing agent = _____ electrons
an oxidizing agent = gains electrons
a reducing agent ______ electrons
a reducing agent loses electrons
True or False
there are no attractive or repulsive forces between particles of real gases
False
there are no attractive or repulsive forces between particles of Ideal gases
Real gases have ____ volume whereas ideal gases have ____ volume
Real gases have small volume whereas ideal gases have no volume
real gases = _____ collision
ideal gases = ______ collision
real gases = inelastic collision
ideal gases = elastic collision
volume is _______ proportional to pressure
volume is inversely proportional to pressure
high V = low P
low V = high P
volume is directly proportional to ______ and _______
temp and number of moles
Ideal Gas law formula
PV = nRT
Combined gas law formula
P1V1/T1 = P2V2/T2
At constant V, as pressure increases, temperature increases
Gay-Lussac’s law
Gay-Lussac’s law formula
P1/T1 = P2/T2
At constant P, as volume increases, temp increases
Charles Law
Charles Law Formula
V1/T1 = V2/T2
At constant T, as pressure increases, volume decreases
Boyles Law
Boyle’s Law formula
P1V1=P2V2
How many steps are there to convert mol to mol
1 step (mol of A to mol of B)
How many steps are there to convert mol to grams?
2 steps (mol A –> mol B –> gB)
How many steps are there to convert grams to mol?
2 steps (gA –> mol A –> mol B)
How many steps are there to convert grams to grams?
3 steps (gA –> mol A –> mol B –> gB)
What is the first step in limiting and excess reactants?
identify ER and LR (divide total number of mols by mols in balanced equation or do mol to gram conversions with product)
How to compute for excess reactants?
Total reacted - theoretical reacted = leftover
Formula of percent yield
%yield = A/T x 100
measurement of randomness of molecules
Entropy (∆S)
amount of heat evolved or absorbed in a reaction carried out at constant pressure
Enthalpy (ΔH)
First Law of Thermodynamics
Energy can never be created or destroyed
Energy can only be converted from one form into another
Second Law of Thermodynamics
Total entropy of the universe always increases
Every spontaneous change is accompanied by an increase in entropy
Third Law of Thermodynamics
At absolute zero, the entropy of a perfect crystalline substance may be taken as zero
Exothermic or Endothermic?
Formation of products is more favorable
Formation of reactants is more favorable
Formation of products is more favorable - Exothermic
Formation of reactants is more favorable - Endothermic
Reaction is spontaneous
Exothermic reaction
Reaction is not spontaneous
Energy absorbed
Endothermic reaction
The relationship between heat energy and temperature is different for every material, and the ___________ is a value that describes how they relate.
specific heat
formula for heat
Q = mcΔT
free energy change for a reaction
Gibbs free energy (ΔG)
reaction that favors the formation of products at the conditions under which the reaction is occurring
Spontaneous reaction
reaction that does not favor the formation of products at the given set of conditions
Nonspontaneous reaction:
formula for change in Gibb’s free energy
ΔG = ΔH - TΔS
ΔG < 0
exergenic
Solution with solute that dissolves until it is unable to dissolve anymore
Leaves undissolved substances at the bottom
Saturated Solution
Less solute than the saturated solution
Solution completely dissolves
No remaining substances
Unsaturated Solution
Has more undissolved solute than the saturated solution Tendency to crystallize and precipitate
Supersaturated Solution
acids turn litmus paper from ____ to _____
blue to red
Molarity formula
M = moles of solute / liters of solution
Molality formula
m = moles of solute / kg solvent
normality formula
N = #H+ or OH- /L of solution
Mass percent solution
mass solute / mass of solution x100
mole fraction
moles of solute/moles of solution
Rate Law Formula
(Concentration)F - (Concentration)I / change in time
Chemical Equilibrium Formula
Kc = (C)^c (D)^d / (A)^ab (B)^b