Initial Fractionation and Properties of Crude Oils Flashcards

1
Q

Why do we use TBP analysis ?

A

It gives the yields and the qualities of the petroleum cuts of a crude oil

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2
Q

What is the BP range for the gas cut ?

A

BP < 0°C

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3
Q

What is the carbon number range for the gas cut ?

A

C1 to C4

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4
Q

What are the different components of the gase cut ?

A
  • refinery fuel gas C1-C2
  • Propane C3
  • Butane C4
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5
Q

What is the BP range for the gasoline cut ?

A

0 < BP < 140-185°C
Light naphtha : 0 < BP < 80-90°C
Heavy nqphthq : 80-90 < BP < 140-185°C

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6
Q

What is the carbon number range for the gasoline cut ?

A

C5 to C10/C11

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7
Q

What are the three subcuts of the gasoline cut ?

A
  • iC5
  • light naphtha C5-C6
  • heavy naphtha C7-C10/11
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8
Q

What are the possible outputs of light naphthas ?

A
  • Gasoline Base (RON 60-80)
  • Petrochemical base (after desiopentanizer)
  • Isomerization
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9
Q

What are the possibles outputs of the heavy naphthas ?

A

Catalytic reforming to sharply increaseoctane number

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10
Q

What is the BP range of the kerosene cut ?

A

185 < BP < 220-240°C

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11
Q

What is the carbon number range for the kerosene cut ?

A

C9/11 to C13/14

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12
Q

What is the average sulfur and mercaptants content in the kerosen cut ?

A

0.01 < sulfur content < 0.3 wt %

10 < mercaptants < 300 ppm

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13
Q

What are the possibles outputs of the kerosene cut ?

A
  • Jet fuel

- Gazole base if S content low enough

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14
Q

What is the BP range of the gasoil cut ?

A

220-240 < BP < 350-380°C

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15
Q

What is the carbon number range of the gasoil cut ?

A

C13/14 to C20/25

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16
Q

What are the possible outputs of the Gasoils cuts ?

A

Hydrodesulfurization

17
Q

What is the BP range of the VGO cuts ?

A

350-380 < BP < 550-600°C

18
Q

What is the carbon number range of the VGO cuts ?

A

C20/25 to C50

19
Q

What are the possible outputs of the VGO cuts ?

A
  • FCC (good gasoline yield)
  • HCK (gasoline, kerosene, gasoil)
  • Lube oil Manufacturing
20
Q

Which impurities need to be closely monitored to be able to exploit VGOs ?

A

No metal content not to poison catalysts

21
Q

What are the possible outputs of the vacuum residue ?

A
  • Bitumens
  • Lube oil plant
  • Thermal conversion
  • Catalytic conversion
22
Q

What are the possible thermal conversions possible for vacuum residue ?

A
  • Visbreaker (25% yield)
  • Coker (70% yield)
  • Flexicoker (no solid coke)
23
Q

What is the limitation ot use catalytic conversion of vacuum residue ?

A

Low Metal Content or hydrotreatment first