Hydrogen bonding Flashcards
In a water molecule, both…
the oxygen and
hydrogen atoms attract the shared electrons in
the covalent bond (electronegativity)
Oxygen atom is more…
electronegative than the
hydrogen atoms.
- distinct ends with partial charge (polar)
– hydrogen bond
Hydrogen bond:
the attractive interaction
between dipoles when the
– positive end of one dipole is a hydrogen atom
bonded to an atom of high electronegativity,
most commonly O or N, and
– the negative end of the other dipole is an atom with
a lone pair of electrons, most commonly O or N
The strength of hydrogen bonding is:
approximately 2-5 kcalmol -1
– for water, it is 5 kcalmol-1
Water’s polarity and subsequent hydrogen
bonding gives rise to…
unique properties.
– Cohesion and adhesion
– HIGH specific heat and heat of vaporization
– Ice is less dense
– A very versatile solvent (dissolver
intermolecular hydrogen bonding result in…
Physical properties of ice and water
Hydrogen in polar covalent bonds is…
attracted to nearby electronegative atoms
(O or N)
Weak electrostatic bonds
– easily broken
Hydrogen bonds are very important in…
biology. Examples:
– properties of water
– protein folding
– DNA and RNA folding
– Temperature regulation