Hydrocarbons Flashcards
Hydrocarbons
Made of hydrogen and carbon only, Balancing reactions: carbon —> hydrogen —> oxygen
Types of hydrocarbons
Types: Aliphatic (straight chain), Alicyclic (ring)- not in course, Aromatic (benzene, C6H6)
Types of aliphatics
Alkane- Saturated (single bonds), CnH2n+2, Alkene- unsaturated, CnH2n, Alkyne- unsaturated, triple bond (not in course)
Alkanes properties
Structural isomers (same number of carbons)
Physical properties: Low melting and boiling point- as chain length increases (larger surface area), melting/boiling point increases due to stronger dispersion forces, Low density- as chain length increases, density increases, Insoluble in water as they are non-polar and water is polar
Chemical properties: Undergo combustion reactions- complete produces CO2 and lots of energy, incomplete produces CO, Substitution reactions- swap hydrogen for halogen, use a catalyst of UV light
Alkenes properties
Structural and geometric isomers,
Physical properties (same as all covalent molecules are the same): Low melting and boiling point- as chain length increases (larger surface area), melting/boiling point increases due to stronger dispersion forces, Low density- as chain length increases, density increases, Insoluble in water as they are non-polar and water is polar
Chemical properties:
Undergo combustion reactions, Addition reactions- breaks double bond
Aromantic (benzene)
Each carbon is covalently bonded to 2 carbons and 1 hydrogen, 4th electron is delocalised allowing it to move freely between orbitals
Aromantic (benzene) properties
Physical properties: Can’t conduction electricity as it is a discrete molecule, Low melting and boiling point however high considering it’s a small molecule because it has a high surface area allowing molecules to get closer together, increasing dispersion forces, Higher density then expected due to molecules being able to get close, Insoluble in water
Chemical properties: Combustion reactions, Substitution reactions
Alcohol group
Hydroxyl group (-OH), suffix- ol
Aldehydes group
Carbonyl group (-CHO with carbon-oxygen double bond), suffix- al, always on carbon 1
Ketone group
Carbonyl group (-CO-), suffix- one
Carboxylic acid group
Carboxyl group (-COOH), suffix- oic acid, always on carbon 2
Esters group
Alkyl group attached to oxygen, suffix- oate, always on carbon 1