Acids and bases Flashcards
Properties of acids
Turn blue litmus paper and universal indicator red, Good electrolytes (strong acids are the best), Corrosive and taste sour, React with reactive metals (redox reaction), React with carbonates, hydrogencarbonates, metal oxides and metal hydroxides (neutralisation reaction)
Properties of bases
Turn red litmus paper and universal indicator blue, Good electrolytes, Caustic and taste bitter, React with acids and ammonium salts (neutralisation reaction)
Davy theory
First theory created that is no longer used, Stated that acids are substances that contain replaceable hydrogens (hydrogens that could be partly or totally replaced by metals) which was incorrect and only applied in redox reactions, not acid-base reactions, States that bases were substances that reaction with acids to form salts and water which is correct
Arrhenius theory
Not used to explain in year 12, Stated that acids release hydrogen ions in solution, States that bases release hydroxide ions in solution, Theory was restricted as not all acids and bases are in solutions
Bronsted-Lowry theory
Stated that acids are proton donors and bases are proton acceptors, In an equation and acid becomes a conjugate base and a base becomes conjugate acid, H3O+ is formed easily as water has an uneven charge distribution meaning the H+ ion is attracted to the lone pair of electrons in H20
Ionisation
when a molecule reacts to form ions (no ions exist before the reaction)
Dissociation
when an ionic compound dissolves and releases ions (ions already exist)
Strong acids
Fully ionise, Represented by a single arrow as reaction goes to completion, Strength is described in terms of the position of equilibrium, HCl, HNO3, H2SO4, HClO4, HBr, HI (unless stated all other acids are assumed weak)
Weak acids
Partially ionise (small Ka, usually less than 1), Represented by a double arrow as reaction doesn’t go to completion, CH3COOH, H3PO4, H2CO3
Strong bases
Dissociate in water releasing OH-, Represented by a single arrow, Oxides and group 1 and 2 hydroxides
Weak bases
Ionise in water (react to form OH-), Represented by a double arrow, NH3, CO3 2-, HCO3-
Strength
Degree of ionisation
Concentration
How much solute is present
Monoprotic acid
1 mol releases 1 mol of H+ when reacted with a strong base, HCl, HNO3, CH3COOH
Diprotic acid
1 mol releases 2 mols of H+ when reacted with a strong base, H2SO4, H2CO3