Harmonic oscillator Flashcards

1
Q

Classical Hooke’s law

A

F = -kx, where;
F is force, Newtons
x is distance, m
k is the spring constant#
- value as it is a restoring force

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2
Q

Newtons 2nd law and Hooke’s law:

A

F=ma=m(d^2x/dt^2)=-kx

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3
Q

Energy stored in vibration

A

V = ∫-Fdx=∫kxdx=1/2kx^2

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4
Q

Harmonic spring general equation

A

x = Asin(wt+phi)
Where A is a constant, w is the angular velocity (rads^-1) and phi is phase

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5
Q

Force with harmonic equation

A

F=ma=m(d^2x/dt^2)=-mw^2Asin(wt+phi)=-mw^2x=-kx

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6
Q

Angular velocity as a function of spring constant and mass

A

w = (k/m)^1/2, found from force with harmonic

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7
Q

Frequency of vibration

A

v^ = w/2pi = 1/2pi*(k/m)^1/2

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8
Q

Boundary condition

A

no infinitely large compressions or extensions

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9
Q

Consequence of boundary

A

E = (v+1/2)hv^=(v+1/2)ℏw where v is a quantum number v = 0,1,2,3…
v^ is the vibrational frequency and w is angular velocity

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10
Q

Is vibrational energy quantised

A

Yes as v is a quantum number v=0,1,2,3… and is a multiple of E

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11
Q

Zero point for vibration:

A

Occurs at v = 0, E = 1/2ℏw,
not 0 as particle is confined

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12
Q

Hv for v=0

A

1

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13
Q

Hv for v=1

A

ζ

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14
Q

Hv for v=2

A

4ζ^2 -2

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15
Q

ζ =

A

x/a

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16
Q

a^4 =

A

ℏ^2/km

17
Q

Ψ for harmonic oscillator

A

Ψ =Hv*e^(ζ^2/2)

18
Q

How to help determine wavefunction

A

Rearrange Schrodinger’s for d^2Ψ/dx^2 + rest = 0

19
Q

What happens for larger masses and stiffer strings?

A

Wavefunction will decay more rapidly due to ζ dependence on k and m

20
Q

What happens to the behaviour of the probability distribution as v (Qnum) increases

A

Position of high probability will migrate towards turning points, more like classical mechanics