Halogenoalkanes Flashcards
What happens in a nucleophilic substitution reaction
A nucleophile attacked a polar molecule, kicks out its functional group and settles itself down in its place
What is a nucleophile
Electron pair donor
Halogenoalkane + hydroxide —>
Alcohol
R-X + -OH –>
ROH + X-
Halogenoalkane + ethanolic potassium cyanide –>
Heat under reflux
Nitrile
Describe a nucleophilic substitution reaction with a potassium cyanide nucleophile
CN attacks the carbon
Arrow goes from carbon to halogen bond
Halogen kicked off and replaced with CN
Halogenoalkane + excess ethanolic ammonia –>
Amine
Where does a nucleophile always attack first in a nucleophilic substitution reaction
Carbon atom
Halogenoalkane + hydroxide ions dissolved in ethanol –>
Heat under reflux
Alkene
Halogenoalkane to alkene mechanism
Elimination
Describe an elimination mechanism
Nucleophile attacks H atom
Arrow from H-C bond to C-C bond
Arrow from C-halogen bond to halogen
Forms C=C bond with no halogen
Halogenoalkane + ethanol under reflux causes which mechanism
Elimination
Halogenoalkane + water under reflux causes which mechanism
Nucleophilic substitution